Abstract
In the solid solution layer double hydroxides with the general composition [Ni1-xAlx(OH)2] [(CO3)x/2·yH2O], 0 ≤ x ≤ 0.4 the Ni2+/Al3+ ions decorate a positively charged triangular lattice that is sandwiched between two hydroxyl layers to form brucite-like host layers. Guest layers of co-intercalated water molecules and carbonate anions oriented with their three-fold axes perpendicular to the basal plane occupy the galleries. For x = 0.30, the carbonate ions form a (√13 × √13)R13.9° in-plane superlattice structure relative to the host layers which themselves exhibit an ABC stacking sequence that is only slightly (20%) disordered. Despite their commensurate structure, the guest layers yield Warren line shape X-ray reflections characteristic of a random stacking arrangement. This unusual result is attributed to the high (26-fold) degeneracy of the ground state structure of the guest layer.
Original language | English (US) |
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Pages (from-to) | 835-839 |
Number of pages | 5 |
Journal | Solid State Communications |
Volume | 101 |
Issue number | 11 |
DOIs | |
State | Published - Mar 1997 |
Externally published | Yes |
Keywords
- A. insulators
- C. crystal structure and symmetry
- D. order-disorder effects
- X-ray scattering
ASJC Scopus subject areas
- General Chemistry
- Condensed Matter Physics
- Materials Chemistry