@article{dd385a4b336e456399f55cad97238c5b,
title = "Radiation tolerance and microstructural changes of nanocrystalline Cu-Ta alloy to high dose self-ion irradiation",
abstract = "Nanocrystalline materials are known to possess excellent radiation resistance due to high fraction of grain boundaries that act as defect sinks, provided they are microstructurally stable at such extreme conditions. In this work, radiation response of a stable nanocrystalline Cu-Ta alloy is studied by irradiating with 4 MeV copper ions to doses (close to the surface) of 1 displacements per atom (dpa) at room temperature (RT); 10 dpa at RT, 573 and 723 K; 100 and 200 dpa at RT and 573 K. Nanoindentation results carried out for samples irradiated till 100 dpa at RT and 573 K show exceptionally low radiation hardening behavior compared to various candidate materials from literature. Results from microstructural characterization, using atom probe analysis and transmission electron microscopy, show a stable nanocrystalline microstructure with minimal grain growth and a meagre swelling in samples irradiated to 100 dpa (~0.2%) and 200 dpa at RT, while no voids in those at 573 K. This radiation tolerance is partly attributed to the stability of Ta nanoclusters due to phase separating nature of the alloy. Additionally, the larger tantalum particles are observed to undergo ballistic dissolution at doses greater than 100 dpa and are eventually precipitated as nanoclusters, replenishing the sink strength, which enhanced material's radiation tolerance when exposed to high irradiation doses and elevated temperatures.",
keywords = "Immiscible system, Irradiation effect, Nanocrystalline, Phase stability, Transmission electron microscopy",
author = "S. Srinivasan and C. Kale and Hornbuckle, {B. C.} and Darling, {K. A.} and Chancey, {M. R.} and E. Hern{\'a}ndez-Rivera and Y. Chen and Koenig, {T. R.} and Wang, {Y. Q.} and Thompson, {G. B.} and Solanki, {K. N.}",
note = "Funding Information: Ion irradiation was performed at the Center for Integrated Nanotechnologies (CINT), an Office of Science User Facility operated for the U.S. Department of Energy (DOE) Office of Science. Los Alamos National Laboratory, an affirmative action equal opportunity employer, is managed by Triad National Security, LLC for the U.S. Department of Energy's NNSA, under contract 89233218CNA000001. S.S., C.K. and K. N. S. acknowledge the use of facilities within the LeRoy Eyring Center for Solid State Science at Arizona State University and Atom probe facility at CAMECA Inc. This work was supported by US Army Research Laboratory under contract W911NF-15-2-0038 and the National Science Foundation No. 1663287 . K.A.D acknowledges A.J Roberts, M. Gallagher, and T. Luckenbaugh for synthesis of the Cu-Ta powder. Funding Information: Ion irradiation was performed at the Center for Integrated Nanotechnologies (CINT), an Office of Science User Facility operated for the U.S. Department of Energy (DOE) Office of Science. Los Alamos National Laboratory, an affirmative action equal opportunity employer, is managed by Triad National Security, LLC for the U.S. Department of Energy's NNSA, under contract 89233218CNA000001. S.S. C.K. and K. N. S. acknowledge the use of facilities within the LeRoy Eyring Center for Solid State Science at Arizona State University and Atom probe facility at CAMECA Inc. This work was supported by US Army Research Laboratory under contract W911NF-15-2-0038 and the National Science Foundation No. 1663287. K.A.D acknowledges A.J Roberts, M. Gallagher, and T. Luckenbaugh for synthesis of the Cu-Ta powder. Publisher Copyright: {\textcopyright} 2020 Acta Materialia Inc.",
year = "2020",
month = aug,
day = "15",
doi = "10.1016/j.actamat.2020.05.061",
language = "English (US)",
volume = "195",
pages = "621--630",
journal = "Acta Materialia",
issn = "1359-6454",
publisher = "Elsevier Limited",
}