Quantitative measurement of short compositional profiles using analytical transmission electron microscopy

E. Meissner, Thomas Sharp, S. Chakraborty

Research output: Contribution to journalArticle

22 Citations (Scopus)

Abstract

Analytical transmission electron microscopy (ATEM) was used to quantitatively measure sub-micrometer compositional profiles produced experimentally by Fe-Mg interdiffusion experiments in olivine. Although analysis of minerals by ATEM is common, compositional profiles suitable for quantitative modeling of diffusion are not generally measured in minerals with ATEM. To demonstrate the suitability of ATEM for diffusion studies in minerals, we have investigated Fe-Mg interdiffusion in experimentally annealed olivine. Because the compositional gradients were induced under well-controlled laboratory conditions, the accuracy of the measurements could be tested by comparing compositional profiles measured by both ATEM and EMPA as well as by retrieving diffusion coefficients from both TEM and EMPA data. The agreement in diffusion coefficients shows that point defect equilibration in the interfacial region of the diffusion couple occurs extremely rapidly at 1200°C. The ability to obtain diffusion data from such short anneals enables various experiments that were not previously possible - for example, to study diffusion rates at high pressures where long fO2 buffered anneals are not generally feasible. ATEM profile measurement is compared with other techniques such as SIMS and RBS and some limitations and applications of ATEM profile measurements are also discussed.

Original languageEnglish (US)
Pages (from-to)546-552
Number of pages7
JournalAmerican Mineralogist
Volume83
Issue number5-6
StatePublished - 1998
Externally publishedYes

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transmission electron microscopy
Transmission electron microscopy
profiles
Minerals
minerals
olivine
mineral
diffusion coefficient
Point defects
Secondary ion mass spectrometry
point defects
secondary ion mass spectrometry
defect
micrometers
experiment
Experiments
gradients
modeling

ASJC Scopus subject areas

  • Geochemistry and Petrology
  • Geophysics

Cite this

Quantitative measurement of short compositional profiles using analytical transmission electron microscopy. / Meissner, E.; Sharp, Thomas; Chakraborty, S.

In: American Mineralogist, Vol. 83, No. 5-6, 1998, p. 546-552.

Research output: Contribution to journalArticle

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