Production of 2-Octenyl Radicals from the Fe(III)● Bleomycin-Mediated Fragmentation of 10-Hydroperoxy-8,12-octadecadienoic Acid

Anand Natrajan; Sidney M. Hecht

doi:10.1021/jo00018a002

Production of 2-Octenyl Radicals from the Fe(III)● Bleomycin-Mediated Fragmentation of 10-Hydroperoxy-8,12-octadecadienoic Acid

Anand Natrajan, Sidney M. Hecht

Research output: Contribution to journal › Article › peer-review

9 Scopus citations

Abstract

The Fe(III)-BLM-mediated fragmentation of 10-hydroperoxy-8,12-octadecadienoic acid was demonstrated unambiguously to occur via homolytic O–O bond scission.

Original language	English (US)
Pages (from-to)	5239-5241
Number of pages	3
Journal	Journal of Organic Chemistry
Volume	56
Issue number	18
DOIs	https://doi.org/10.1021/jo00018a002
State	Published - Aug 1 1991
Externally published	Yes

ASJC Scopus subject areas

Organic Chemistry

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@article{b1c91ba195ed483fa1e26103046519ef,

title = "Production of 2-Octenyl Radicals from the Fe(III)● Bleomycin-Mediated Fragmentation of 10-Hydroperoxy-8,12-octadecadienoic Acid",

abstract = "The Fe(III)-BLM-mediated fragmentation of 10-hydroperoxy-8,12-octadecadienoic acid was demonstrated unambiguously to occur via homolytic O–O bond scission.",

author = "Anand Natrajan and Hecht, {Sidney M.}",

year = "1991",

month = aug,

day = "1",

doi = "10.1021/jo00018a002",

language = "English (US)",

volume = "56",

pages = "5239--5241",

journal = "Journal of Organic Chemistry",

issn = "0022-3263",

publisher = "American Chemical Society",

number = "18",

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T1 - Production of 2-Octenyl Radicals from the Fe(III)● Bleomycin-Mediated Fragmentation of 10-Hydroperoxy-8,12-octadecadienoic Acid

AU - Natrajan, Anand

AU - Hecht, Sidney M.

PY - 1991/8/1

Y1 - 1991/8/1

N2 - The Fe(III)-BLM-mediated fragmentation of 10-hydroperoxy-8,12-octadecadienoic acid was demonstrated unambiguously to occur via homolytic O–O bond scission.

AB - The Fe(III)-BLM-mediated fragmentation of 10-hydroperoxy-8,12-octadecadienoic acid was demonstrated unambiguously to occur via homolytic O–O bond scission.

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U2 - 10.1021/jo00018a002

DO - 10.1021/jo00018a002

M3 - Article

AN - SCOPUS:0013281895

SN - 0022-3263

VL - 56

SP - 5239

EP - 5241

JO - Journal of Organic Chemistry

JF - Journal of Organic Chemistry

IS - 18

ER -

Production of 2-Octenyl Radicals from the Fe(III)● Bleomycin-Mediated Fragmentation of 10-Hydroperoxy-8,12-octadecadienoic Acid

Abstract

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