Preparation, characterization and oxygen gas sensitivity of nanosolid superacid SO4 2-/ LaCoFeO4

De Juan Lin, Shui Fa Shen, Qing Hua Wang, Lin Jie Wang, Nai Sheng Chen, Jin Ling Huang

Research output: Chapter in Book/Report/Conference proceedingConference contribution

1 Scopus citations

Abstract

Metal oxides have been applied in gas sensor technology while suffering poor sensitivity and high working temperature. In this work, a novel method has been adopted to improve these problems of the sensors. A mixture of Fe 3+, La3+, Co2+ (Fe3+: La3+: Co 2+ =10:3:1) and dispersing agent in water solution was precipitated by adding NH4 +(pH=9) under agitation. The precipitate was filtered, washed and drying, then immersed with 0.5M (NH4)2SO4 in 12hr. Superacid SO4 2-/ LaCoFeO4 was prepared after calcined at 673K for 1h. The thick film units for oxygen sensor were dintered at 673K for 3h.The structure of this catalyst has been characterized by means of powder X-ray diffraction (XRD), transmission electron microscope (TEM), IR, X-ray photoelectron spectroscopy (XPS) and specific surface area measurements. The result indicated that the SO4 2-/ LaCoFeO4 grain sizes (≤10nm) were smaller and the specific surface area (126M 2/g ) was higher than the pure metal oxide LaCoFeO4. The acid strength was measured by the model reaction of ethyl acetate synthesis and attributed as superacid. In addition, the SO4 2- was combined with metal ions in a bidentate fashion. The binding energy of SO 4 2-/LaCoFeO4 was larger than that of LaCoFeO4. The sensitivity as well as the working temperature is improved by comparison with the pure LaCoFeO4 phase. The relationship between the oxygen sensing properties and structure has also been discussed.

Original languageEnglish (US)
Title of host publicationFrontier of Nanoscience and Technology
Pages209-213
Number of pages5
DOIs
StatePublished - Aug 30 2011
Externally publishedYes
Event2011 International Conference on Frontier of Nanoscience and Technology, ICFNST 2011 - Kunming, China
Duration: Sep 28 2011Sep 29 2011

Publication series

NameMaterials Science Forum
Volume694
ISSN (Print)0255-5476

Other

Other2011 International Conference on Frontier of Nanoscience and Technology, ICFNST 2011
CountryChina
CityKunming
Period9/28/119/29/11

Keywords

  • Binding energy.
  • Chelating bidentate
  • Nanosolid superacid
  • SO /LaCoFeO oxygen gas sensitivity

ASJC Scopus subject areas

  • Materials Science(all)
  • Condensed Matter Physics
  • Mechanics of Materials
  • Mechanical Engineering

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    Lin, D. J., Shen, S. F., Wang, Q. H., Wang, L. J., Chen, N. S., & Huang, J. L. (2011). Preparation, characterization and oxygen gas sensitivity of nanosolid superacid SO4 2-/ LaCoFeO4. In Frontier of Nanoscience and Technology (pp. 209-213). (Materials Science Forum; Vol. 694). https://doi.org/10.4028/www.scientific.net/MSF.694.209