Prediction of entropy and dynamic properties of water below the homogeneous nucleation temperature

Francis W. Starr; Charles Angell; H. Eugene Stanley

doi:10.1016/S0378-4371(03)00012-8

Prediction of entropy and dynamic properties of water below the homogeneous nucleation temperature

Francis W. Starr, Charles Angell, H. Eugene Stanley

Molecular Sciences, School of (SMS)

Research output: Contribution to journal › Article › peer-review

122 Scopus citations

Abstract

The behavior of thermodynamic properties of liquid water at atmospheric pressure and below homogeneous nucleation temperature was investigated. In this regard, the excess entropy measurement of the liquid over the crystal within relatively narrow limits was estimated. On inital cooling below the melting temperature the water appeared to be fragile, but near the glass transition region it was strong.

Original language	English (US)
Pages (from-to)	51-66
Number of pages	16
Journal	Physica A: Statistical Mechanics and its Applications
Volume	323
DOIs	https://doi.org/10.1016/S0378-4371(03)00012-8
State	Published - May 15 2003

ASJC Scopus subject areas

Statistical and Nonlinear Physics
Statistics and Probability

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title = "Prediction of entropy and dynamic properties of water below the homogeneous nucleation temperature",

abstract = "The behavior of thermodynamic properties of liquid water at atmospheric pressure and below homogeneous nucleation temperature was investigated. In this regard, the excess entropy measurement of the liquid over the crystal within relatively narrow limits was estimated. On inital cooling below the melting temperature the water appeared to be fragile, but near the glass transition region it was strong.",

author = "Starr, {Francis W.} and Charles Angell and Stanley, {H. Eugene}",

note = "Funding Information: We thank R.J. Speedy for his invaluable contributions. We also thank B.D. Kay, C.T. Moynihan, P.H. Poole, S. Sastry, F. Sciortino, and R.S. Smith for enlightening discussions. CAA acknowledges support form a NSF Solid State Chemistry grant DMR 9108028-002. The Center for Polymer Studies is supported by NSF grant CHE-0096892.",

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doi = "10.1016/S0378-4371(03)00012-8",

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T1 - Prediction of entropy and dynamic properties of water below the homogeneous nucleation temperature

AU - Starr, Francis W.

AU - Angell, Charles

AU - Stanley, H. Eugene

N1 - Funding Information: We thank R.J. Speedy for his invaluable contributions. We also thank B.D. Kay, C.T. Moynihan, P.H. Poole, S. Sastry, F. Sciortino, and R.S. Smith for enlightening discussions. CAA acknowledges support form a NSF Solid State Chemistry grant DMR 9108028-002. The Center for Polymer Studies is supported by NSF grant CHE-0096892.

PY - 2003/5/15

Y1 - 2003/5/15

N2 - The behavior of thermodynamic properties of liquid water at atmospheric pressure and below homogeneous nucleation temperature was investigated. In this regard, the excess entropy measurement of the liquid over the crystal within relatively narrow limits was estimated. On inital cooling below the melting temperature the water appeared to be fragile, but near the glass transition region it was strong.

AB - The behavior of thermodynamic properties of liquid water at atmospheric pressure and below homogeneous nucleation temperature was investigated. In this regard, the excess entropy measurement of the liquid over the crystal within relatively narrow limits was estimated. On inital cooling below the melting temperature the water appeared to be fragile, but near the glass transition region it was strong.

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U2 - 10.1016/S0378-4371(03)00012-8

DO - 10.1016/S0378-4371(03)00012-8

M3 - Article

AN - SCOPUS:0037513411

SN - 0378-4371

VL - 323

SP - 51

EP - 66

JO - Physica A: Statistical Mechanics and its Applications

JF - Physica A: Statistical Mechanics and its Applications

ER -

Prediction of entropy and dynamic properties of water below the homogeneous nucleation temperature

Abstract

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