Predicted Performance of High-Efficiency Photovoltaics with Energy-Selective Front Reflectors for Photon Recycling Enhancements

Eric Y. Chen, Sean J. Babcock, Richard R. King

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Abstract

Energy-selective mirrors that reflect photons below a specific energy, e.g. radiatively emitted photons from the cell at the cell bandgap, back towards the solar cell enhance solar cell efficiencies via photon recycling by generating higher open-circuit voltages. The internal front reflectors are designed to admit sunlight for photogeneration at all energies above a given threshold energy above the bandgap energy, while remaining highly reflective for energies at or near the solar cell bandgap. Predicted cell performance is modeled using detailed balance and semi-empirical methods to determine optimal reflector energies for maximum cell efficiency enhancements and effects non-radiative recombination on efficiency. Improved open circuit voltages are predicted at the highest front reflectance values with energies 0.25 eV above that of the cell bandgap. For Si cells, increases of up to 2% in maximum cell efficiency corresponding to Voc increase of 0.2 V can be achieved in single-junction solar cells approaching 33% when combined with appropriate front reflector architectures such as Bragg reflectors or dielectric stacks that restrict black body emission. For GaAs cells, up to 9% can be gained with angle emission restriction.

Original languageEnglish (US)
Title of host publication2019 IEEE 46th Photovoltaic Specialists Conference, PVSC 2019
PublisherInstitute of Electrical and Electronics Engineers Inc.
Pages1737-1742
Number of pages6
ISBN (Electronic)9781728104942
DOIs
StatePublished - Jun 2019
Event46th IEEE Photovoltaic Specialists Conference, PVSC 2019 - Chicago, United States
Duration: Jun 16 2019Jun 21 2019

Publication series

NameConference Record of the IEEE Photovoltaic Specialists Conference
ISSN (Print)0160-8371

Conference

Conference46th IEEE Photovoltaic Specialists Conference, PVSC 2019
CountryUnited States
CityChicago
Period6/16/196/21/19

Keywords

  • angle restriction
  • blackbody emission
  • dielectric stacks
  • front reflector
  • photon recycling

ASJC Scopus subject areas

  • Control and Systems Engineering
  • Industrial and Manufacturing Engineering
  • Electrical and Electronic Engineering

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  • Cite this

    Chen, E. Y., Babcock, S. J., & King, R. R. (2019). Predicted Performance of High-Efficiency Photovoltaics with Energy-Selective Front Reflectors for Photon Recycling Enhancements. In 2019 IEEE 46th Photovoltaic Specialists Conference, PVSC 2019 (pp. 1737-1742). [8980942] (Conference Record of the IEEE Photovoltaic Specialists Conference). Institute of Electrical and Electronics Engineers Inc.. https://doi.org/10.1109/PVSC40753.2019.8980942