POLY(ALKYL METHACRYLATE-METHACRYLATE CARBOXYLATE) ION-CONTAINING BLOCK COPOLYMERS.

T. E. Long, C. D. DePorter, N. Patel, D. W. Dwight, G. L. Wilkes, J. E. McGrath

Research output: Contribution to journalConference articlepeer-review

14 Scopus citations

Abstract

All-acrylic block copolymer precursors can be synthesized via anionic techniques demonstrating predictable molecular weights and narrow molecular weight distributions. Poly(2-ethylhexyl methacrylate) can possess such desirable properties as a low glass transition temperature, alkane solubility, and a hydrophobic character. Quantitative hydrolysis of poly(t-butyl methacrylate) blocks allows for very distinct hydrophobic-hydrophilic block copolymers. The derived ion-containing block copolymers will serve as excellent model systems for the elucidation of structure-property relationships. It is believed that the extent and mechanisms of coulombic aggregation will be significantly different than the corresponding random systems.

Original languageEnglish (US)
Pages (from-to)214-216
Number of pages3
JournalAmerican Chemical Society, Polymer Preprints, Division of Polymer Chemistry
Volume28
Issue number2
StatePublished - Aug 1987
Externally publishedYes
EventPolym Prepr -Pap Presented at the New Orleans, LA Meet - New Orleans, LA, USA
Duration: Aug 30 1987Sep 4 1987

ASJC Scopus subject areas

  • Polymers and Plastics

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