Polarized fluorescence spectra of retinol ad diphenyl octatetraene

Thomas A. Moore, Pill soon Song

Research output: Contribution to journalArticle

28 Scopus citations

Abstract

The polarization of fluorescence excitation and emission bands of all-trans retinol in 77°K has been measured at relatively high resolution. The main excitation band as well as the fluorescence band showed a degree of polarization approaching that the theoretical maximum of 0.5 for a linear oscillator under photoselective conditions. These results are consistent with the assignment that the main absorption and fluorescence bands originate from the long-axis polarized iB ← IA transition, as expected from free electron theory. Diphenyl octatetraene was also studied, yielding results similar to the retinol system.

Original languageEnglish (US)
Pages (from-to)128-130
Number of pages3
JournalChemical Physics Letters
Volume19
Issue number1
DOIs
StatePublished - 1973
Externally publishedYes

ASJC Scopus subject areas

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

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