Plasmonic Measurement of Electron Transfer between a Single Metal Nanoparticle and an Electrode through a Molecular Layer

Ruihong Liu, Xiaonan Shan, Hui Wang, Nongjian Tao

Research output: Contribution to journalArticle

Abstract

We study electron transfer associated with electrocatalytic reduction of hydrogen on single platinum nanoparticles separated from an electrode surface with an alkanethiol monolayer using a plasmonic imaging technique. By varying the monolayer thickness, we show that the reaction rate depends on electron tunneling from the electrode to the nanoparticle. The tunneling decay constant is ∼4.3 nm-1, which is small compared to those in literature for alkanethiols. We attribute it to a reduced tunneling barrier resulting from biasing the electrode potential negatively to the hydrogen reduction regime. In addition to allowing study of electron transfer of single nanoparticles, the work demonstrates an optical method to measure charge transport in molecules electrically wired to two electrodes.

Original languageEnglish (US)
Pages (from-to)11694-11699
Number of pages6
JournalJournal of the American Chemical Society
Volume141
Issue number29
DOIs
StatePublished - Jul 24 2019

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Metal Nanoparticles
Metal nanoparticles
Electrodes
Electrons
Nanoparticles
Hydrogen
Monolayers
Electron tunneling
Platinum
Reaction rates
Charge transfer
Imaging techniques
Molecules

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

Cite this

Plasmonic Measurement of Electron Transfer between a Single Metal Nanoparticle and an Electrode through a Molecular Layer. / Liu, Ruihong; Shan, Xiaonan; Wang, Hui; Tao, Nongjian.

In: Journal of the American Chemical Society, Vol. 141, No. 29, 24.07.2019, p. 11694-11699.

Research output: Contribution to journalArticle

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