Physicochemical characterization of zeolites SSZ-26 and SSZ-33

R. F. Lobo, M. Pan, I. Chan, R. C. Medrud, S. I. Zones, P. A. Crozier, M. E. Davis

Research output: Contribution to journalArticle

66 Scopus citations

Abstract

Detailed characterization of zeolites SSZ-26 and SSZ-33 is presented and includes data from adsorption experiments, X-ray powder diffraction (XRD), electron diffraction (ED), and high-resolution electron microscopy (HREM). Simulated XRD patterns and HREM images of the proposed structures agree very well with all the experimental data. These zeolites are the first synthetic high-silica molecular sieves to contain a three-dimensional pore system comprised of intersecting 10- and 12-ring pores. The structures of SSZ-26 and SSZ-33 are compared to the structures of known zeolites, and the relationships between the geometry of the structure-directing agents used in the synthesis of SSZ-26 and the geometry of the pores are analyzed using energy minimization calculations. Several hypothetical zeolite structures are derived based on the proposed models for SSZ-26 and SSZ-33. SSZ-26 and SSZ-33 are the first examples of molecular sieves whose multidimensional pore systems have been formed by the purposeful design of their structure-directing agents.

Original languageEnglish (US)
Pages (from-to)12040-12052
Number of pages13
JournalJournal of physical chemistry
Volume98
Issue number46
DOIs
StatePublished - 1994

ASJC Scopus subject areas

  • Engineering(all)
  • Physical and Theoretical Chemistry

Fingerprint Dive into the research topics of 'Physicochemical characterization of zeolites SSZ-26 and SSZ-33'. Together they form a unique fingerprint.

  • Cite this

    Lobo, R. F., Pan, M., Chan, I., Medrud, R. C., Zones, S. I., Crozier, P. A., & Davis, M. E. (1994). Physicochemical characterization of zeolites SSZ-26 and SSZ-33. Journal of physical chemistry, 98(46), 12040-12052. https://doi.org/10.1021/j100097a033