Photocatalytic reduction of cadmium on TiO2 nanoparticles modified with amino acids

Ivanka A. Ruvarac-Bugarčić, Zoran V. Šaponjić, Slavica Zec, Tijana Rajh, Jovan M. Nedeljković

Research output: Contribution to journalArticlepeer-review

17 Scopus citations

Abstract

The photocatalytic reduction of cadmium ions was investigated using TiO2 nanoparticles (45 Å in diameter) surface-modified with histidine (His) or alanine (Ala). The X-ray diffraction measurements indicated that illumination of suspension consisting of His- or Ala-modified TiO 2 nanoparticles in the presence of cadmium ions under an anoxic atmosphere lead to the formation of metallic cadmium. The TiO2 Fermi level upon surface modification with His or Ala must be shifted towards negative potentials at least 400 mV in order to achieve efficient photoreduction of cadmium ions. The surface structure of His- or Ala-modified TiO2 nanoparticles was proposed based on the changes in the vibration spectrum of His or Ala after adsorption on TiO2 and after addition of cadmium ions.

Original languageEnglish (US)
Pages (from-to)110-113
Number of pages4
JournalChemical Physics Letters
Volume407
Issue number1-3
DOIs
StatePublished - May 17 2005
Externally publishedYes

ASJC Scopus subject areas

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

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