Phase equilibria of the lead-magnesium-titanate and lead-niobium-titanate systems at 1000°C and 1 atm

Robert Mangham; William Petuskey

Phase equilibria of the lead-magnesium-titanate and lead-niobium-titanate systems at 1000°C and 1 atm

Robert Mangham, William Petuskey

Molecular Sciences, School of (SMS)

Research output: Contribution to journal › Conference article › peer-review

1 Scopus citations

Abstract

Phase equilibria of the PbO-MgO-TiO ₂ and PbO-Nb ₂O ₅-TiO ₂ systems have been experimentally determined at 1000°C and 1 atm pressure. This work is part of an overall comprehensive thermal analysis of the ferroelectric relaxor system Pb(Mg _1/3Nb _2/3)O ₃-PbTiO ₃. In the PbO-MgO-TiO ₂ system, lead titanate equilibrates with each of the magnesium titanates, MgO and a titania saturated liquid lead oxide. The most significant feature in the PbO-Nb ₂O ₅-TiO ₂ system is the extent of solid solution of the lead and oxygen-defect pyrochlore phase, Pb ₃(Nb _1-xTi _x) ₄O ₁₃, in which titanium dissolution is as much as x = 0.394 (or ∼22.5 cation % Ti ⁴⁺).

Original language	English (US)
Pages (from-to)	139-149
Number of pages	11
Journal	Ceramic Transactions
Volume	169
State	Published - Aug 22 2005
Event	106th Annual Meeting of the American Ceramic Society - Indianapolis, IN, United States Duration: Apr 18 2004 → Apr 21 2004

ASJC Scopus subject areas

Ceramics and Composites
Materials Chemistry

Cite this

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title = "Phase equilibria of the lead-magnesium-titanate and lead-niobium-titanate systems at 1000°C and 1 atm",

abstract = "Phase equilibria of the PbO-MgO-TiO 2 and PbO-Nb 2O 5-TiO 2 systems have been experimentally determined at 1000°C and 1 atm pressure. This work is part of an overall comprehensive thermal analysis of the ferroelectric relaxor system Pb(Mg 1/3Nb 2/3)O 3-PbTiO 3. In the PbO-MgO-TiO 2 system, lead titanate equilibrates with each of the magnesium titanates, MgO and a titania saturated liquid lead oxide. The most significant feature in the PbO-Nb 2O 5-TiO 2 system is the extent of solid solution of the lead and oxygen-defect pyrochlore phase, Pb 3(Nb 1-xTi x) 4O 13, in which titanium dissolution is as much as x = 0.394 (or ∼22.5 cation % Ti 4+).",

author = "Robert Mangham and William Petuskey",

year = "2005",

month = aug,

day = "22",

language = "English (US)",

volume = "169",

pages = "139--149",

journal = "Ceramic Transactions",

issn = "1042-1122",

publisher = "American Ceramic Society",

note = "106th Annual Meeting of the American Ceramic Society ; Conference date: 18-04-2004 Through 21-04-2004",

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TY - JOUR

T1 - Phase equilibria of the lead-magnesium-titanate and lead-niobium-titanate systems at 1000°C and 1 atm

AU - Mangham, Robert

AU - Petuskey, William

PY - 2005/8/22

Y1 - 2005/8/22

N2 - Phase equilibria of the PbO-MgO-TiO 2 and PbO-Nb 2O 5-TiO 2 systems have been experimentally determined at 1000°C and 1 atm pressure. This work is part of an overall comprehensive thermal analysis of the ferroelectric relaxor system Pb(Mg 1/3Nb 2/3)O 3-PbTiO 3. In the PbO-MgO-TiO 2 system, lead titanate equilibrates with each of the magnesium titanates, MgO and a titania saturated liquid lead oxide. The most significant feature in the PbO-Nb 2O 5-TiO 2 system is the extent of solid solution of the lead and oxygen-defect pyrochlore phase, Pb 3(Nb 1-xTi x) 4O 13, in which titanium dissolution is as much as x = 0.394 (or ∼22.5 cation % Ti 4+).

AB - Phase equilibria of the PbO-MgO-TiO 2 and PbO-Nb 2O 5-TiO 2 systems have been experimentally determined at 1000°C and 1 atm pressure. This work is part of an overall comprehensive thermal analysis of the ferroelectric relaxor system Pb(Mg 1/3Nb 2/3)O 3-PbTiO 3. In the PbO-MgO-TiO 2 system, lead titanate equilibrates with each of the magnesium titanates, MgO and a titania saturated liquid lead oxide. The most significant feature in the PbO-Nb 2O 5-TiO 2 system is the extent of solid solution of the lead and oxygen-defect pyrochlore phase, Pb 3(Nb 1-xTi x) 4O 13, in which titanium dissolution is as much as x = 0.394 (or ∼22.5 cation % Ti 4+).

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M3 - Conference article

AN - SCOPUS:23744448844

SN - 1042-1122

VL - 169

SP - 139

EP - 149

JO - Ceramic Transactions

JF - Ceramic Transactions

T2 - 106th Annual Meeting of the American Ceramic Society

Y2 - 18 April 2004 through 21 April 2004

ER -

Phase equilibria of the lead-magnesium-titanate and lead-niobium-titanate systems at 1000°C and 1 atm

Abstract

ASJC Scopus subject areas

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