Perspective on the glass transition

Research output: Contribution to journalArticle

831 Scopus citations

Abstract

Some of the reasons for the current interest in the phenomenology of vitrification are reviewed and progress due to, as well as limitations of, mode coupling theories (MCT) for viscosity divergence are examined. Liquids which fit the MCT predictions best are also those with the most imminent Kauzmann entropy crises near the glass transition temperature, Tg. Mode coupling predictions break down far above Tg at the point, Tx, where Goldstein long ago argued that activated processes controlled by the (3N + 1)-dimensional potential energy surface for the N- particle system should become dominant. Examining behavior in the energy topology-controlled regime, we note that ergodicity-breaking is not simply a consequence of viscosity divergence. In the liquids best fitting MCT, which are at the fragile extreme of liquid behavior, shear and structural relaxation processes slowly decouple below Tx, leading to breakdown of the Adam-Gibbs equation for viscosity. The latter in its original and derived Vogel-Fulcher forms remains valid for enthalpy (and presumably volume) relaxation processes. The distinction between strong and fragile behavior in liquids is related to the density of configurational states (minima) characterizing the potential energy surface.

Original languageEnglish (US)
Pages (from-to)863-871
Number of pages9
JournalJournal of Physics and Chemistry of Solids
Volume49
Issue number8
DOIs
StatePublished - 1988
Externally publishedYes

Keywords

  • Glass transition
  • Kauzmann paradox
  • configurational states
  • mode coupling
  • viscosity divergence

ASJC Scopus subject areas

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

Fingerprint Dive into the research topics of 'Perspective on the glass transition'. Together they form a unique fingerprint.

  • Cite this