Permanent electric dipole moments of metal containing molecules

Research output: Contribution to journalArticle

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Abstract

A summary of the current status of experimentally derived values of the permanent electric dipole moment, μ, for the 3s, 4s, 5s, and 6s series of transient metal containing molecules is given. The experimental methods employed are described with particular emphasis placed upon optical Stark measurements of supersonic molecular beam samples. The complications associated with the analysis of optical Stark spectra of open shell polyatomic metal containing radicals are addressed. An assessment of the applicability of simple molecular orbital correlation diagrams to predict trends in measured values of μ for early transition metal diatomic molecules is made.

Original languageEnglish (US)
Pages (from-to)455-477
Number of pages23
JournalInternational Reviews in Physical Chemistry
Volume19
Issue number3
DOIs
StatePublished - 2000

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Electric dipole moments
electric moments
electric dipoles
dipole moments
Metals
Molecules
Molecular beams
Molecular orbitals
diatomic molecules
metals
molecular beams
Transition metals
molecules
molecular orbitals
transition metals
diagrams
trends

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry

Cite this

Permanent electric dipole moments of metal containing molecules. / Steimle, Timothy.

In: International Reviews in Physical Chemistry, Vol. 19, No. 3, 2000, p. 455-477.

Research output: Contribution to journalArticle

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