Oxygen isotope measurements of seawater ( H2 18O/H2 16O): A comparison of cavity ring-down spectroscopy (CRDS) and isotope ratio mass spectrometry (IRMS)

S. A. Walker, K. Azetsu-Scott, C. Normandeau, D. E. Kelley, R. Friedrich, R. Newton, Peter Schlosser, J. L. Mckay, W. Abdi, E. Kerrigan, S. E. Craig, D. W.R. Wallace

Research output: Contribution to journalArticle

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Abstract

Laser-based spectroscopic techniques, such as cavity ring-down spectroscopy (CRDS), provide a new, cost effective and more widely available approach to measure the oxygen isotope ratio in water molecules, H2 18O/ H2 16O (δ18O), and are used increasingly to measure δ18O in the world's oceans. Here, we present results from an interlaboratory comparison designed to evaluate the quality of CRDS-derived measurements, and their consistency with values measured by isotope ratio mass spectrometry (IRMS). We also discuss the influence of salt on instrument performance and sample throughput for the analysis of seawater samples. This study compared measurements of δ18O from natural samples with a wide range of salinities (0, 29.4, and 34.6) performed by four independent labs: two using CRDS and two using IRMS. We also compared δ18O measurements of Northeast Atlantic Deep Water collected in 2013, 2012, 2009, and 1995 from the AR7W repeat hydrography transect across the Labrador Sea. The within-lab precision of ocean-based CRDS measurements is seen to approach 0.03‰, which is better than the manufacturer's typically stated analytical precision (around +/- 0.05‰), and comparable to that achievable with IRMS. The interlaboratory differences of measurements (highest-lowest) reported by the four labs is taken as an indicator of overall accuracy, and is estimated conservatively as being<0.1‰, with the potential to approach 0.05‰. Overall, these results show that CRDS based 18O measurements of seawater can be equivalent to high-quality measurements by IRMS.

Original languageEnglish (US)
Pages (from-to)31-38
Number of pages8
JournalLimnology and Oceanography: Methods
Volume14
Issue number1
DOIs
StatePublished - Jan 1 2016
Externally publishedYes

Fingerprint

Seawater
Isotopes
Mass spectrometry
Spectroscopy
Oxygen
Water
Throughput
Salts
Molecules
Lasers
Costs

ASJC Scopus subject areas

  • Ocean Engineering

Cite this

Oxygen isotope measurements of seawater ( H2 18O/H2 16O) : A comparison of cavity ring-down spectroscopy (CRDS) and isotope ratio mass spectrometry (IRMS). / Walker, S. A.; Azetsu-Scott, K.; Normandeau, C.; Kelley, D. E.; Friedrich, R.; Newton, R.; Schlosser, Peter; Mckay, J. L.; Abdi, W.; Kerrigan, E.; Craig, S. E.; Wallace, D. W.R.

In: Limnology and Oceanography: Methods, Vol. 14, No. 1, 01.01.2016, p. 31-38.

Research output: Contribution to journalArticle

Walker, SA, Azetsu-Scott, K, Normandeau, C, Kelley, DE, Friedrich, R, Newton, R, Schlosser, P, Mckay, JL, Abdi, W, Kerrigan, E, Craig, SE & Wallace, DWR 2016, 'Oxygen isotope measurements of seawater ( H2 18O/H2 16O): A comparison of cavity ring-down spectroscopy (CRDS) and isotope ratio mass spectrometry (IRMS)', Limnology and Oceanography: Methods, vol. 14, no. 1, pp. 31-38. https://doi.org/10.1002/lom3.10067
Walker, S. A. ; Azetsu-Scott, K. ; Normandeau, C. ; Kelley, D. E. ; Friedrich, R. ; Newton, R. ; Schlosser, Peter ; Mckay, J. L. ; Abdi, W. ; Kerrigan, E. ; Craig, S. E. ; Wallace, D. W.R. / Oxygen isotope measurements of seawater ( H2 18O/H2 16O) : A comparison of cavity ring-down spectroscopy (CRDS) and isotope ratio mass spectrometry (IRMS). In: Limnology and Oceanography: Methods. 2016 ; Vol. 14, No. 1. pp. 31-38.
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AU - Normandeau, C.

AU - Kelley, D. E.

AU - Friedrich, R.

AU - Newton, R.

AU - Schlosser, Peter

AU - Mckay, J. L.

AU - Abdi, W.

AU - Kerrigan, E.

AU - Craig, S. E.

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