Orientation-averaged light-extinction characteristics of compound particles including aggregate effects

Research output: Contribution to journalArticle

1 Citation (Scopus)

Abstract

Orientation-averaged light-extinction characteristics of compound sulfate-carbon-soot particles have been analyzed with a discrete-dipole algorithm (DDSCAT code) for r1/r2 (ratio of primary-particle radius to secondary-particle radius) in the range 7 to 1 and for wavelengths from 0.4 to 0.8 μm. It was found that compound particles above a particle radius of approximately 0.2 μm exhibit light-extinction characteristics that closely match those of a pure sulfate particle. The shielding of the carbon particle by the primary particle apparently reduces the absorption effect of the soot particle over the range of all possible orientations. In light of the fact that soot particles tend to be small in comparison with host sulfate particles, the light-extinction characteristics of compound particles are dictated by the optical properties of the host particles. This result has been applied for aerosol aggregates with log-normal size distributions. For r1/r2 ≥ 2 the aggregate extinction coefficient of a group of compound particles remains within 12% of that of a group consisting only of sulfate particles. This allows for effective calculation of the overall aerosol light extinction on the basis of the optical and geometrical properties of the constituent particles without having to include a compound-geometry effect.

Original languageEnglish (US)
Pages (from-to)514-517
Number of pages4
JournalJournal of the Optical Society of America A: Optics and Image Science, and Vision
Volume22
Issue number3
DOIs
StatePublished - 2005

Fingerprint

Light extinction
Soot
Sulfates
Aerosols
Carbon
Shielding
Particles (particulate matter)
Optical properties
Wavelength
Geometry

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Computer Vision and Pattern Recognition

Cite this

@article{722df96d7c2e47f5a353c47048b20695,
title = "Orientation-averaged light-extinction characteristics of compound particles including aggregate effects",
abstract = "Orientation-averaged light-extinction characteristics of compound sulfate-carbon-soot particles have been analyzed with a discrete-dipole algorithm (DDSCAT code) for r1/r2 (ratio of primary-particle radius to secondary-particle radius) in the range 7 to 1 and for wavelengths from 0.4 to 0.8 μm. It was found that compound particles above a particle radius of approximately 0.2 μm exhibit light-extinction characteristics that closely match those of a pure sulfate particle. The shielding of the carbon particle by the primary particle apparently reduces the absorption effect of the soot particle over the range of all possible orientations. In light of the fact that soot particles tend to be small in comparison with host sulfate particles, the light-extinction characteristics of compound particles are dictated by the optical properties of the host particles. This result has been applied for aerosol aggregates with log-normal size distributions. For r1/r2 ≥ 2 the aggregate extinction coefficient of a group of compound particles remains within 12{\%} of that of a group consisting only of sulfate particles. This allows for effective calculation of the overall aerosol light extinction on the basis of the optical and geometrical properties of the constituent particles without having to include a compound-geometry effect.",
author = "Taewoo Lee",
year = "2005",
doi = "10.1364/JOSAA.22.000514",
language = "English (US)",
volume = "22",
pages = "514--517",
journal = "Journal of the Optical Society of America. A, Optics and image science",
issn = "0740-3232",
publisher = "The Optical Society",
number = "3",

}

TY - JOUR

T1 - Orientation-averaged light-extinction characteristics of compound particles including aggregate effects

AU - Lee, Taewoo

PY - 2005

Y1 - 2005

N2 - Orientation-averaged light-extinction characteristics of compound sulfate-carbon-soot particles have been analyzed with a discrete-dipole algorithm (DDSCAT code) for r1/r2 (ratio of primary-particle radius to secondary-particle radius) in the range 7 to 1 and for wavelengths from 0.4 to 0.8 μm. It was found that compound particles above a particle radius of approximately 0.2 μm exhibit light-extinction characteristics that closely match those of a pure sulfate particle. The shielding of the carbon particle by the primary particle apparently reduces the absorption effect of the soot particle over the range of all possible orientations. In light of the fact that soot particles tend to be small in comparison with host sulfate particles, the light-extinction characteristics of compound particles are dictated by the optical properties of the host particles. This result has been applied for aerosol aggregates with log-normal size distributions. For r1/r2 ≥ 2 the aggregate extinction coefficient of a group of compound particles remains within 12% of that of a group consisting only of sulfate particles. This allows for effective calculation of the overall aerosol light extinction on the basis of the optical and geometrical properties of the constituent particles without having to include a compound-geometry effect.

AB - Orientation-averaged light-extinction characteristics of compound sulfate-carbon-soot particles have been analyzed with a discrete-dipole algorithm (DDSCAT code) for r1/r2 (ratio of primary-particle radius to secondary-particle radius) in the range 7 to 1 and for wavelengths from 0.4 to 0.8 μm. It was found that compound particles above a particle radius of approximately 0.2 μm exhibit light-extinction characteristics that closely match those of a pure sulfate particle. The shielding of the carbon particle by the primary particle apparently reduces the absorption effect of the soot particle over the range of all possible orientations. In light of the fact that soot particles tend to be small in comparison with host sulfate particles, the light-extinction characteristics of compound particles are dictated by the optical properties of the host particles. This result has been applied for aerosol aggregates with log-normal size distributions. For r1/r2 ≥ 2 the aggregate extinction coefficient of a group of compound particles remains within 12% of that of a group consisting only of sulfate particles. This allows for effective calculation of the overall aerosol light extinction on the basis of the optical and geometrical properties of the constituent particles without having to include a compound-geometry effect.

UR - http://www.scopus.com/inward/record.url?scp=15044350191&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=15044350191&partnerID=8YFLogxK

U2 - 10.1364/JOSAA.22.000514

DO - 10.1364/JOSAA.22.000514

M3 - Article

VL - 22

SP - 514

EP - 517

JO - Journal of the Optical Society of America. A, Optics and image science

JF - Journal of the Optical Society of America. A, Optics and image science

SN - 0740-3232

IS - 3

ER -