Organic aerosol composition in yosemite national park during the 2002 yosemite aerosol characterization study

Guenter Engling, Pierre Herckes, Jacqueline Carrillo, Sonia M. Kreidenweis, Jeffrey L. Collett

Research output: Chapter in Book/Report/Conference proceedingConference contribution

1 Citation (Scopus)

Abstract

The Yosemite Aerosol Characterization Study (YACS) was conducted during the summer of 2002 in order to investigate the sources of regional haze in Yosemite National Park by characterizing the physicochemical properties of the ambient aerosol. In particular, the influence of wildfires on summer haze and the resulting impact on visibility were investigated. Samples were collected on quartz fiber filters with PM2.5, PM10, and multi-stage high-volume collectors. Speciation of the organic aerosol fraction was achieved by gas chromatography with mass spectrometric detection, following solvent extraction. Average concentrations of particulate organic species were determined from weekly composite samples. In addition, daily samples were analyzed to better characterize trends in organic carbon species and source contributions during intensive haze periods. Organic carbon dominated the PM2.5 mass, accounting for more than 70% of the total fine mass on average. In addition, radiocarbon measurements indicated that on average more than 90% of the fine organic carbon mass was contributed by contemporary sources. Wildfires had a significant influence on PM2.5 during certain episodes, as determined by high concentrations of wood smoke markers and confirmed by complementary methods, including back trajectory analysis, satellite images and black carbon signature. Secondary biogenic compounds represented an important additional source of contemporary carbon, as indicated by relatively high concentrations of pinene oxidation products. The investigation of particle size distributions of a variety of organic compounds revealed interesting patterns. While some compounds were present in particles of a wider size range (super- and sub-micron particles), others, including dicarboxylic acids and certain pinene oxidation products, were detected only in sub-micrometer particles. Overall, fine aerosol in Yosemite National Park during the summer of 2002 was dominated by natural sources, in particular by smoke from wildfires and secondary organic species of biogenic origin.

Original languageEnglish (US)
Title of host publicationRegional and Global Perspectives on Haze
Pages419-429
Number of pages11
Volume134 VIP
StatePublished - 2004
Externally publishedYes
EventRegional and Global Perspectives on Haze: Causes, Consequences and Controversies Visibility Specialty Conference - Asheville, NC, United States
Duration: Oct 25 2004Oct 29 2004

Other

OtherRegional and Global Perspectives on Haze: Causes, Consequences and Controversies Visibility Specialty Conference
CountryUnited States
CityAsheville, NC
Period10/25/0410/29/04

Fingerprint

Aerosols
Organic carbon
Chemical analysis
Smoke
Dust collectors
Oxidation
Solvent extraction
Carbon black
Organic compounds
Visibility
Particle size analysis
Gas chromatography
Particles (particulate matter)
Quartz
Wood
Trajectories
Satellites
Carbon
Acids
Fibers

Keywords

  • Aerosol
  • Haze
  • Levoglucosan
  • Molecular markers
  • Particulate organic matter (POM)
  • PM
  • Secondary organic aerosol (SOA)
  • Wood smoke

ASJC Scopus subject areas

  • Engineering(all)

Cite this

Engling, G., Herckes, P., Carrillo, J., Kreidenweis, S. M., & Collett, J. L. (2004). Organic aerosol composition in yosemite national park during the 2002 yosemite aerosol characterization study. In Regional and Global Perspectives on Haze (Vol. 134 VIP, pp. 419-429)

Organic aerosol composition in yosemite national park during the 2002 yosemite aerosol characterization study. / Engling, Guenter; Herckes, Pierre; Carrillo, Jacqueline; Kreidenweis, Sonia M.; Collett, Jeffrey L.

Regional and Global Perspectives on Haze. Vol. 134 VIP 2004. p. 419-429.

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Engling, G, Herckes, P, Carrillo, J, Kreidenweis, SM & Collett, JL 2004, Organic aerosol composition in yosemite national park during the 2002 yosemite aerosol characterization study. in Regional and Global Perspectives on Haze. vol. 134 VIP, pp. 419-429, Regional and Global Perspectives on Haze: Causes, Consequences and Controversies Visibility Specialty Conference, Asheville, NC, United States, 10/25/04.
Engling G, Herckes P, Carrillo J, Kreidenweis SM, Collett JL. Organic aerosol composition in yosemite national park during the 2002 yosemite aerosol characterization study. In Regional and Global Perspectives on Haze. Vol. 134 VIP. 2004. p. 419-429
Engling, Guenter ; Herckes, Pierre ; Carrillo, Jacqueline ; Kreidenweis, Sonia M. ; Collett, Jeffrey L. / Organic aerosol composition in yosemite national park during the 2002 yosemite aerosol characterization study. Regional and Global Perspectives on Haze. Vol. 134 VIP 2004. pp. 419-429
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abstract = "The Yosemite Aerosol Characterization Study (YACS) was conducted during the summer of 2002 in order to investigate the sources of regional haze in Yosemite National Park by characterizing the physicochemical properties of the ambient aerosol. In particular, the influence of wildfires on summer haze and the resulting impact on visibility were investigated. Samples were collected on quartz fiber filters with PM2.5, PM10, and multi-stage high-volume collectors. Speciation of the organic aerosol fraction was achieved by gas chromatography with mass spectrometric detection, following solvent extraction. Average concentrations of particulate organic species were determined from weekly composite samples. In addition, daily samples were analyzed to better characterize trends in organic carbon species and source contributions during intensive haze periods. Organic carbon dominated the PM2.5 mass, accounting for more than 70{\%} of the total fine mass on average. In addition, radiocarbon measurements indicated that on average more than 90{\%} of the fine organic carbon mass was contributed by contemporary sources. Wildfires had a significant influence on PM2.5 during certain episodes, as determined by high concentrations of wood smoke markers and confirmed by complementary methods, including back trajectory analysis, satellite images and black carbon signature. Secondary biogenic compounds represented an important additional source of contemporary carbon, as indicated by relatively high concentrations of pinene oxidation products. The investigation of particle size distributions of a variety of organic compounds revealed interesting patterns. While some compounds were present in particles of a wider size range (super- and sub-micron particles), others, including dicarboxylic acids and certain pinene oxidation products, were detected only in sub-micrometer particles. Overall, fine aerosol in Yosemite National Park during the summer of 2002 was dominated by natural sources, in particular by smoke from wildfires and secondary organic species of biogenic origin.",
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AB - The Yosemite Aerosol Characterization Study (YACS) was conducted during the summer of 2002 in order to investigate the sources of regional haze in Yosemite National Park by characterizing the physicochemical properties of the ambient aerosol. In particular, the influence of wildfires on summer haze and the resulting impact on visibility were investigated. Samples were collected on quartz fiber filters with PM2.5, PM10, and multi-stage high-volume collectors. Speciation of the organic aerosol fraction was achieved by gas chromatography with mass spectrometric detection, following solvent extraction. Average concentrations of particulate organic species were determined from weekly composite samples. In addition, daily samples were analyzed to better characterize trends in organic carbon species and source contributions during intensive haze periods. Organic carbon dominated the PM2.5 mass, accounting for more than 70% of the total fine mass on average. In addition, radiocarbon measurements indicated that on average more than 90% of the fine organic carbon mass was contributed by contemporary sources. Wildfires had a significant influence on PM2.5 during certain episodes, as determined by high concentrations of wood smoke markers and confirmed by complementary methods, including back trajectory analysis, satellite images and black carbon signature. Secondary biogenic compounds represented an important additional source of contemporary carbon, as indicated by relatively high concentrations of pinene oxidation products. The investigation of particle size distributions of a variety of organic compounds revealed interesting patterns. While some compounds were present in particles of a wider size range (super- and sub-micron particles), others, including dicarboxylic acids and certain pinene oxidation products, were detected only in sub-micrometer particles. Overall, fine aerosol in Yosemite National Park during the summer of 2002 was dominated by natural sources, in particular by smoke from wildfires and secondary organic species of biogenic origin.

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