Optimization of [Bmim][HSO4]-Catalyzed Transesterification of Camelina Oil

Huan Li; Tian Ma; Zhensheng Shen; An Li; Jie Yang; Dong Xiang; Jiuyi Liu; Shuguang Deng; Yingqiang Sun

doi:10.1002/ceat.201900477

Optimization of [Bmim][HSO₄]-Catalyzed Transesterification of Camelina Oil

Huan Li, Tian Ma, Zhensheng Shen, An Li, Jie Yang, Dong Xiang, Jiuyi Liu, Shuguang Deng, Yingqiang Sun

Engineering of Matter, Transport and Energy, School for (SEMTE)

Research output: Contribution to journal › Article › peer-review

1 Scopus citations

Abstract

1-Butyl-3-methylimidazolium hydrogen sulfate ([Bmim][HSO₄]) is utilized to catalyze transesterification of camelina oil with methanol. The major compositions of camelina biodiesel are saturated fatty acid esters (C16:0, C18:0), monounsaturated, and polyunsaturated fatty acid esters (C18:2, C18:3). The effects of reaction temperature, reaction time, M_methanol:M_{Camelina oil}, and M_[Bmim][HSO4]:M_{Camelina oil} on biodiesel production are investigated in detail, and a general mathematical model is developed to well predict the biodiesel yield. Also, [Bmim][HSO₄] is thermally stable to recycle for four times with a high biodiesel yield. The fuel properties of camelina biodiesel are all comparable to the American Society for Testing Materials (ASTM) standards.

Original language	English (US)
Pages (from-to)	403-411
Number of pages	9
Journal	Chemical Engineering and Technology
Volume	43
Issue number	3
DOIs	https://doi.org/10.1002/ceat.201900477
State	Published - Mar 1 2020

Keywords

Camelina oil
Ionic liquids
Transesterification
[Bmim][HSO]

ASJC Scopus subject areas

Chemistry(all)
Chemical Engineering(all)
Industrial and Manufacturing Engineering

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@article{0351babefcc446fc9ea2a763a86075fb,

title = "Optimization of [Bmim][HSO4]-Catalyzed Transesterification of Camelina Oil",

abstract = "1-Butyl-3-methylimidazolium hydrogen sulfate ([Bmim][HSO4]) is utilized to catalyze transesterification of camelina oil with methanol. The major compositions of camelina biodiesel are saturated fatty acid esters (C16:0, C18:0), monounsaturated, and polyunsaturated fatty acid esters (C18:2, C18:3). The effects of reaction temperature, reaction time, Mmethanol:MCamelina oil, and M[Bmim][HSO4]:MCamelina oil on biodiesel production are investigated in detail, and a general mathematical model is developed to well predict the biodiesel yield. Also, [Bmim][HSO4] is thermally stable to recycle for four times with a high biodiesel yield. The fuel properties of camelina biodiesel are all comparable to the American Society for Testing Materials (ASTM) standards.",

keywords = "Camelina oil, Ionic liquids, Transesterification, [Bmim][HSO]",

author = "Huan Li and Tian Ma and Zhensheng Shen and An Li and Jie Yang and Dong Xiang and Jiuyi Liu and Shuguang Deng and Yingqiang Sun",

note = "Funding Information: The authors are grateful for financial support from the Anhui University Talent Startup Fund China Y040418343, the Research Foundation from the College of Chemistry and Chemical Engineering of the Anhui University, the Anhui Provincial Natural Science Foundation China 1908085QB70, and the National Natural Science Foundation of China 21706001. The authors have declared no conflict of interest. Funding Information: The authors are grateful for financial support from the Anhui University Talent Startup Fund China Y040418343, the Research Foundation from the College of Chemistry and Chemical Engineering of the Anhui University, the Anhui Provincial Natural Science Foundation China 1908085QB70, and the National Natural Science Foundation of China 21706001. The authors have declared no conflict of interest . ",

year = "2020",

month = mar,

day = "1",

doi = "10.1002/ceat.201900477",

language = "English (US)",

volume = "43",

pages = "403--411",

journal = "Chemical Engineering and Technology",

issn = "0930-7516",

publisher = "Wiley-VCH Verlag",

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TY - JOUR

T1 - Optimization of [Bmim][HSO4]-Catalyzed Transesterification of Camelina Oil

AU - Li, Huan

AU - Ma, Tian

AU - Shen, Zhensheng

AU - Li, An

AU - Yang, Jie

AU - Xiang, Dong

AU - Liu, Jiuyi

AU - Deng, Shuguang

AU - Sun, Yingqiang

N1 - Funding Information: The authors are grateful for financial support from the Anhui University Talent Startup Fund China Y040418343, the Research Foundation from the College of Chemistry and Chemical Engineering of the Anhui University, the Anhui Provincial Natural Science Foundation China 1908085QB70, and the National Natural Science Foundation of China 21706001. The authors have declared no conflict of interest. Funding Information: The authors are grateful for financial support from the Anhui University Talent Startup Fund China Y040418343, the Research Foundation from the College of Chemistry and Chemical Engineering of the Anhui University, the Anhui Provincial Natural Science Foundation China 1908085QB70, and the National Natural Science Foundation of China 21706001. The authors have declared no conflict of interest .

PY - 2020/3/1

Y1 - 2020/3/1

N2 - 1-Butyl-3-methylimidazolium hydrogen sulfate ([Bmim][HSO4]) is utilized to catalyze transesterification of camelina oil with methanol. The major compositions of camelina biodiesel are saturated fatty acid esters (C16:0, C18:0), monounsaturated, and polyunsaturated fatty acid esters (C18:2, C18:3). The effects of reaction temperature, reaction time, Mmethanol:MCamelina oil, and M[Bmim][HSO4]:MCamelina oil on biodiesel production are investigated in detail, and a general mathematical model is developed to well predict the biodiesel yield. Also, [Bmim][HSO4] is thermally stable to recycle for four times with a high biodiesel yield. The fuel properties of camelina biodiesel are all comparable to the American Society for Testing Materials (ASTM) standards.

AB - 1-Butyl-3-methylimidazolium hydrogen sulfate ([Bmim][HSO4]) is utilized to catalyze transesterification of camelina oil with methanol. The major compositions of camelina biodiesel are saturated fatty acid esters (C16:0, C18:0), monounsaturated, and polyunsaturated fatty acid esters (C18:2, C18:3). The effects of reaction temperature, reaction time, Mmethanol:MCamelina oil, and M[Bmim][HSO4]:MCamelina oil on biodiesel production are investigated in detail, and a general mathematical model is developed to well predict the biodiesel yield. Also, [Bmim][HSO4] is thermally stable to recycle for four times with a high biodiesel yield. The fuel properties of camelina biodiesel are all comparable to the American Society for Testing Materials (ASTM) standards.

KW - Camelina oil

KW - Ionic liquids

KW - Transesterification

KW - [Bmim][HSO]

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