TY - JOUR
T1 - One-step synthesis and structure of an oligo(spiro-orthocarbonate)
AU - Vodak, David T.
AU - Braun, Matthew
AU - Iordanidis, Lykourgos
AU - Plévert, Jacques
AU - Stevens, Michael
AU - Beck, Larry
AU - Spence, John
AU - O'Keeffe, Michael
AU - Yaghi, Omar M.
PY - 2002/5/8
Y1 - 2002/5/8
N2 - The reaction of pentaerythritol and tetraethylorthocarbonate at 260 °C for 12 h yields a white crystalline material that was characterized by 13C CPMAS NMR, CHN analysis, FT-IR, electron and X-ray powder diffraction, and Rietveld analysis. The white crystalline material was found to have the formula C6H8O4 and a crystal structure with a monoclinic cell [a = 9.167 Å, b = 5.681 Å, c = 5.880 Å, β = 90.0°, space group I2] of hexagonally arranged spiro-oligomeric chains.
AB - The reaction of pentaerythritol and tetraethylorthocarbonate at 260 °C for 12 h yields a white crystalline material that was characterized by 13C CPMAS NMR, CHN analysis, FT-IR, electron and X-ray powder diffraction, and Rietveld analysis. The white crystalline material was found to have the formula C6H8O4 and a crystal structure with a monoclinic cell [a = 9.167 Å, b = 5.681 Å, c = 5.880 Å, β = 90.0°, space group I2] of hexagonally arranged spiro-oligomeric chains.
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U2 - 10.1021/ja017683i
DO - 10.1021/ja017683i
M3 - Article
C2 - 11982342
AN - SCOPUS:0037042273
SN - 0002-7863
VL - 124
SP - 4942
EP - 4943
JO - Journal of the American Chemical Society
JF - Journal of the American Chemical Society
IS - 18
ER -