One-step synthesis and structure of an oligo(spiro-orthocarbonate)

David T. Vodak, Matthew Braun, Lykourgos Iordanidis, Jacques Plévert, Michael Stevens, Larry Beck, John Spence, Michael O'Keeffe, Omar M. Yaghi

Research output: Contribution to journalArticle

16 Citations (Scopus)

Abstract

The reaction of pentaerythritol and tetraethylorthocarbonate at 260 °C for 12 h yields a white crystalline material that was characterized by 13C CPMAS NMR, CHN analysis, FT-IR, electron and X-ray powder diffraction, and Rietveld analysis. The white crystalline material was found to have the formula C6H8O4 and a crystal structure with a monoclinic cell [a = 9.167 Å, b = 5.681 Å, c = 5.880 Å, β = 90.0°, space group I2] of hexagonally arranged spiro-oligomeric chains.

Original languageEnglish (US)
Pages (from-to)4942-4943
Number of pages2
JournalJournal of the American Chemical Society
Volume124
Issue number18
DOIs
StatePublished - May 8 2002

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Powder Diffraction
X-Ray Diffraction
Electrons
Crystalline materials
Rietveld analysis
X ray powder diffraction
Crystal structure
Nuclear magnetic resonance
Carbon-13 Magnetic Resonance Spectroscopy
pentaerythritol

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Vodak, D. T., Braun, M., Iordanidis, L., Plévert, J., Stevens, M., Beck, L., ... Yaghi, O. M. (2002). One-step synthesis and structure of an oligo(spiro-orthocarbonate). Journal of the American Chemical Society, 124(18), 4942-4943. https://doi.org/10.1021/ja017683i

One-step synthesis and structure of an oligo(spiro-orthocarbonate). / Vodak, David T.; Braun, Matthew; Iordanidis, Lykourgos; Plévert, Jacques; Stevens, Michael; Beck, Larry; Spence, John; O'Keeffe, Michael; Yaghi, Omar M.

In: Journal of the American Chemical Society, Vol. 124, No. 18, 08.05.2002, p. 4942-4943.

Research output: Contribution to journalArticle

Vodak, DT, Braun, M, Iordanidis, L, Plévert, J, Stevens, M, Beck, L, Spence, J, O'Keeffe, M & Yaghi, OM 2002, 'One-step synthesis and structure of an oligo(spiro-orthocarbonate)', Journal of the American Chemical Society, vol. 124, no. 18, pp. 4942-4943. https://doi.org/10.1021/ja017683i
Vodak DT, Braun M, Iordanidis L, Plévert J, Stevens M, Beck L et al. One-step synthesis and structure of an oligo(spiro-orthocarbonate). Journal of the American Chemical Society. 2002 May 8;124(18):4942-4943. https://doi.org/10.1021/ja017683i
Vodak, David T. ; Braun, Matthew ; Iordanidis, Lykourgos ; Plévert, Jacques ; Stevens, Michael ; Beck, Larry ; Spence, John ; O'Keeffe, Michael ; Yaghi, Omar M. / One-step synthesis and structure of an oligo(spiro-orthocarbonate). In: Journal of the American Chemical Society. 2002 ; Vol. 124, No. 18. pp. 4942-4943.
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