Zur kristallstruktur von O2+MF6- (M = Sb, Ru, Pt, Au)

Translated title of the contribution: On the crystal structure of O2+MF6- (M = Sb, Ru, Pt, Au)

Oliver Graudejus, B. G. Müller

Research output: Contribution to journalArticle

20 Citations (Scopus)

Abstract

O2+MF6- (M = Sb, Ru, Pt, Au) were obtained again, but for the first time investigated by X-ray methods. Colourless O2+SbF6- and the rubyred compounds O2+RuF6- and O2+PtF6- crystallize isostructural in space group Ia3-Th7 (Nr. 206) with a = 1016(1) pm (Sb), a = 1002.6(9) pm (Ru) and a = 1003.6(9) pm (Pt), Z = 8. Yellow O2+AuF6- crystallizes trigonal-rhombohedric in space group R3-D326 (Nr. 148) with a = 775.9(3) pm, c = 711.7(4) pm, Z = 3.

Original languageGerman
Pages (from-to)1076-1082
Number of pages7
JournalZeitschrift fur Anorganische und Allgemeine Chemie
Volume622
Issue number6
StatePublished - Dec 1 1996
Externally publishedYes

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Crystal structure
X rays

Keywords

  • Dioxygenyl compounds
  • Single crystal structure

ASJC Scopus subject areas

  • Inorganic Chemistry

Cite this

Zur kristallstruktur von O2+MF6- (M = Sb, Ru, Pt, Au). / Graudejus, Oliver; Müller, B. G.

In: Zeitschrift fur Anorganische und Allgemeine Chemie, Vol. 622, No. 6, 01.12.1996, p. 1076-1082.

Research output: Contribution to journalArticle

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N2 - O2+MF6- (M = Sb, Ru, Pt, Au) were obtained again, but for the first time investigated by X-ray methods. Colourless O2+SbF6- and the rubyred compounds O2+RuF6- and O2+PtF6- crystallize isostructural in space group Ia3-Th7 (Nr. 206) with a = 1016(1) pm (Sb), a = 1002.6(9) pm (Ru) and a = 1003.6(9) pm (Pt), Z = 8. Yellow O2+AuF6- crystallizes trigonal-rhombohedric in space group R3-D326 (Nr. 148) with a = 775.9(3) pm, c = 711.7(4) pm, Z = 3.

AB - O2+MF6- (M = Sb, Ru, Pt, Au) were obtained again, but for the first time investigated by X-ray methods. Colourless O2+SbF6- and the rubyred compounds O2+RuF6- and O2+PtF6- crystallize isostructural in space group Ia3-Th7 (Nr. 206) with a = 1016(1) pm (Sb), a = 1002.6(9) pm (Ru) and a = 1003.6(9) pm (Pt), Z = 8. Yellow O2+AuF6- crystallizes trigonal-rhombohedric in space group R3-D326 (Nr. 148) with a = 775.9(3) pm, c = 711.7(4) pm, Z = 3.

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