Zur kristallstruktur von O2+MF6- (M = Sb, Ru, Pt, Au)

O. Graudejus; B. G. Müller

doi:10.1002/zaac.19966220623

Zur kristallstruktur von O₂⁺MF₆^- (M = Sb, Ru, Pt, Au)

Translated title of the contribution: On the crystal structure of O₂⁺MF₆^- (M = Sb, Ru, Pt, Au)

O. Graudejus, B. G. Müller

Research output: Contribution to journal › Article › peer-review

24 Scopus citations

Abstract

O₂⁺MF₆^- (M = Sb, Ru, Pt, Au) were obtained again, but for the first time investigated by X-ray methods. Colourless O₂⁺SbF₆^- and the rubyred compounds O₂⁺RuF₆^- and O₂⁺PtF₆^- crystallize isostructural in space group Ia3-T_h⁷ (Nr. 206) with a = 1016(1) pm (Sb), a = 1002.6(9) pm (Ru) and a = 1003.6(9) pm (Pt), Z = 8. Yellow O₂⁺AuF₆^- crystallizes trigonal-rhombohedric in space group R3-D₃₂⁶ (Nr. 148) with a = 775.9(3) pm, c = 711.7(4) pm, Z = 3.

Translated title of the contribution	On the crystal structure of O₂⁺MF₆^- (M = Sb, Ru, Pt, Au)
Original language	German
Pages (from-to)	1076-1082
Number of pages	7
Journal	Zeitschrift fur Anorganische und Allgemeine Chemie
Volume	622
Issue number	6
DOIs	https://doi.org/10.1002/zaac.19966220623
State	Published - 1996
Externally published	Yes

Keywords

Dioxygenyl compounds
Single crystal structure

ASJC Scopus subject areas

Inorganic Chemistry

Access to Document

10.1002/zaac.19966220623

Cite this

@article{d439ea78224245a0bf18a6b70c100a82,

title = "Zur kristallstruktur von O2+MF6- (M = Sb, Ru, Pt, Au)",

abstract = "O2+MF6- (M = Sb, Ru, Pt, Au) were obtained again, but for the first time investigated by X-ray methods. Colourless O2+SbF6- and the rubyred compounds O2+RuF6- and O2+PtF6- crystallize isostructural in space group Ia3-Th7 (Nr. 206) with a = 1016(1) pm (Sb), a = 1002.6(9) pm (Ru) and a = 1003.6(9) pm (Pt), Z = 8. Yellow O2+AuF6- crystallizes trigonal-rhombohedric in space group R3-D326 (Nr. 148) with a = 775.9(3) pm, c = 711.7(4) pm, Z = 3.",

keywords = "Dioxygenyl compounds, Single crystal structure",

author = "O. Graudejus and M{\"u}ller, {B. G.}",

year = "1996",

doi = "10.1002/zaac.19966220623",

language = "German",

volume = "622",

pages = "1076--1082",

journal = "Zeitschrift fur Anorganische und Allgemeine Chemie",

issn = "0044-2313",

publisher = "Wiley-VCH Verlag",

number = "6",

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TY - JOUR

T1 - Zur kristallstruktur von O2+MF6- (M = Sb, Ru, Pt, Au)

AU - Graudejus, O.

AU - Müller, B. G.

PY - 1996

Y1 - 1996

N2 - O2+MF6- (M = Sb, Ru, Pt, Au) were obtained again, but for the first time investigated by X-ray methods. Colourless O2+SbF6- and the rubyred compounds O2+RuF6- and O2+PtF6- crystallize isostructural in space group Ia3-Th7 (Nr. 206) with a = 1016(1) pm (Sb), a = 1002.6(9) pm (Ru) and a = 1003.6(9) pm (Pt), Z = 8. Yellow O2+AuF6- crystallizes trigonal-rhombohedric in space group R3-D326 (Nr. 148) with a = 775.9(3) pm, c = 711.7(4) pm, Z = 3.

AB - O2+MF6- (M = Sb, Ru, Pt, Au) were obtained again, but for the first time investigated by X-ray methods. Colourless O2+SbF6- and the rubyred compounds O2+RuF6- and O2+PtF6- crystallize isostructural in space group Ia3-Th7 (Nr. 206) with a = 1016(1) pm (Sb), a = 1002.6(9) pm (Ru) and a = 1003.6(9) pm (Pt), Z = 8. Yellow O2+AuF6- crystallizes trigonal-rhombohedric in space group R3-D326 (Nr. 148) with a = 775.9(3) pm, c = 711.7(4) pm, Z = 3.

KW - Dioxygenyl compounds

KW - Single crystal structure

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