On graphite and the 2175 Å extinction profile

B. T. Draine, Sangeeta Malhotra

Research output: Contribution to journalArticle

144 Citations (Scopus)

Abstract

Classical electromagnetic theory is used to study the constraints placed on interstellar graphite grains by the observations of Fitzpatrick & Massa (who found large variations in FWHM γ of the bump with minimal, and uncorrelated, variations in the central wavelength λ0). Accurate calculations using the discrete dipole approximation are used to test the accuracy of the commonly used "1/3-2/3 approximation" for graphite spheres. We show that the 1/3-2/3 approximation is sufficiently accurate for use in studying variations in the extinction profile due to changes in graphite grain size or coatings on the grains. We investigate the effect on the 2175 Å extinction profile of (1) changes in size distribution, (2) changes in grain shape, and (3) coatings of ice or other material. We show that all of the above effects produce correlated changes in both γ and λ0. The calculated shifts in λ0 are such that the observed near-constancy of λ0 appears to limit variations in the size, shape, or coatings of small graphite grains. We also investigate the consequences of coagulation with other grains. We find that in the Rayleigh limit, only quite small shifts in λ-1 0 result when a spherical graphite grain is in contact with one or two silicate grains. These shifts are small enough that such coagulation is not ruled out by the observed constancy of λ-1 0. However, such coagulation does not appear able to account for the observed variations in profile width. We conclude that the observed variations in width of the 2175 Å profile cannot be explained by changes in graphite grain size, shape, clumping, or coating, but must instead be due to variations in the dielectric properties of the graphite, due either to impurities, degree of crystallinity, or to surface effects.

Original languageEnglish (US)
Pages (from-to)632-645
Number of pages14
JournalAstrophysical Journal
Volume414
Issue number2
StatePublished - Sep 10 1993
Externally publishedYes

Fingerprint

graphite
extinction
profiles
coating
coagulation
coatings
constancy
shift
grain size
approximation
dielectric property
crystallinity
dielectric properties
silicates
ice
silicate
electromagnetism
dipoles
wavelength
impurities

Keywords

  • Dust, extinction
  • ISM: general
  • Ultraviolet: interstellar

ASJC Scopus subject areas

  • Space and Planetary Science

Cite this

Draine, B. T., & Malhotra, S. (1993). On graphite and the 2175 Å extinction profile. Astrophysical Journal, 414(2), 632-645.

On graphite and the 2175 Å extinction profile. / Draine, B. T.; Malhotra, Sangeeta.

In: Astrophysical Journal, Vol. 414, No. 2, 10.09.1993, p. 632-645.

Research output: Contribution to journalArticle

Draine, BT & Malhotra, S 1993, 'On graphite and the 2175 Å extinction profile', Astrophysical Journal, vol. 414, no. 2, pp. 632-645.
Draine BT, Malhotra S. On graphite and the 2175 Å extinction profile. Astrophysical Journal. 1993 Sep 10;414(2):632-645.
Draine, B. T. ; Malhotra, Sangeeta. / On graphite and the 2175 Å extinction profile. In: Astrophysical Journal. 1993 ; Vol. 414, No. 2. pp. 632-645.
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