Ohaaki reservoir chemistry: Characteristics of an arc-type hydrothermal system in the Taupo Volcanic Zone, New Zealand

Situated along the eastern margin of the Taupo Volcanic Zone (TVZ), the high-gas and high-enthalpy production fluids from the Ohaaki geothermal field are chemically similar to other arc-type volcanic systems found along this part of the TVZ. Two thermal upwellings can be distinguished within the field, each apparently emanating from fault structures in the Mesozoic basement greywackes. Although both plumes have similar salinities and appear to be fully equilibrated with the reservoir rocks containing them, fluids associated with the eastern upflow zone are enriched in B and F compared to those in the western upflow zone. δ²H and δ¹⁸O signatures for water suggest that up to 20% of the water in the discharges may derive from a magmatic source, and a δ²H-Cl trend established by the East-Bank fluids indicate end-member mixing between a high-Cl fluid and Cl-deficient steam containing as much as 40% arc-type vapour. Gas signatures in fluids from the two production fields show compositional differences that cannot be explained by physical reservoir processes. The eastern fluids have higher N₂/Ar and CO₂/He ratios, and consistently higher CH₄-CO₂ ¹³C fractionation temperatures than those in the western upflow zone. In addition, stark differences in ³He/⁴He and ⁴⁰Ar/³⁶Ar ratios for the two production fields suggest two-component mixing for the respective source components, with the eastern fluids having a significantly larger radiogenic gas content than those to the west. Collectively, these signatures suggest the presence of a relatively young and shallowly seated degassing intrusive beneath the eastern upflow zone, perhaps as shallow as 4 km beneath the surface.