Octahedral and tetrahedral co-ordination states of cobalt (II) in molten zinc chloride-aluminium chloride mixtures

C. A. Angell; D. M. Gruen

doi:10.1016/0022-1902(67)80278-1

Octahedral and tetrahedral co-ordination states of cobalt (II) in molten zinc chloride-aluminium chloride mixtures

C. A. Angell, D. M. Gruen

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Abstract

Absorption spectra of Co(II) have been studied in molten mixtures of ZnCl₂ and AlCl₃ both as a function of melt composition and of temperature. The spectral changes have been interpreted in terms of an octahedral-tetrahedral equilibrium involving chloro-complexes of Co(II), analogous to those observed in earlier work on Ni(II) in mixtures of KCl and ZnCl₂.

Original language	English (US)
Pages (from-to)	2243-2247
Number of pages	5
Journal	Journal of Inorganic and Nuclear Chemistry
Volume	29
Issue number	9
DOIs	https://doi.org/10.1016/0022-1902(67)80278-1
State	Published - Sep 1967
Externally published	Yes

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title = "Octahedral and tetrahedral co-ordination states of cobalt (II) in molten zinc chloride-aluminium chloride mixtures",

abstract = "Absorption spectra of Co(II) have been studied in molten mixtures of ZnCl2 and AlCl3 both as a function of melt composition and of temperature. The spectral changes have been interpreted in terms of an octahedral-tetrahedral equilibrium involving chloro-complexes of Co(II), analogous to those observed in earlier work on Ni(II) in mixtures of KCl and ZnCl2.",

author = "Angell, {C. A.} and Gruen, {D. M.}",

year = "1967",

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doi = "10.1016/0022-1902(67)80278-1",

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journal = "Journal of Inorganic and Nuclear Chemistry",

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T1 - Octahedral and tetrahedral co-ordination states of cobalt (II) in molten zinc chloride-aluminium chloride mixtures

AU - Angell, C. A.

AU - Gruen, D. M.

PY - 1967/9

Y1 - 1967/9

N2 - Absorption spectra of Co(II) have been studied in molten mixtures of ZnCl2 and AlCl3 both as a function of melt composition and of temperature. The spectral changes have been interpreted in terms of an octahedral-tetrahedral equilibrium involving chloro-complexes of Co(II), analogous to those observed in earlier work on Ni(II) in mixtures of KCl and ZnCl2.

AB - Absorption spectra of Co(II) have been studied in molten mixtures of ZnCl2 and AlCl3 both as a function of melt composition and of temperature. The spectral changes have been interpreted in terms of an octahedral-tetrahedral equilibrium involving chloro-complexes of Co(II), analogous to those observed in earlier work on Ni(II) in mixtures of KCl and ZnCl2.

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U2 - 10.1016/0022-1902(67)80278-1

DO - 10.1016/0022-1902(67)80278-1

M3 - Article

AN - SCOPUS:33746990886

SN - 0022-1902

VL - 29

SP - 2243

EP - 2247

JO - Journal of Inorganic and Nuclear Chemistry

JF - Journal of Inorganic and Nuclear Chemistry

IS - 9

ER -

Octahedral and tetrahedral co-ordination states of cobalt (II) in molten zinc chloride-aluminium chloride mixtures

Abstract

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