Octahedral and tetrahedral co-ordination states of cobalt (II) in molten zinc chloride-aluminium chloride mixtures

Charles Angell, D. M. Gruen

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18 Citations (Scopus)

Abstract

Absorption spectra of Co(II) have been studied in molten mixtures of ZnCl2 and AlCl3 both as a function of melt composition and of temperature. The spectral changes have been interpreted in terms of an octahedral-tetrahedral equilibrium involving chloro-complexes of Co(II), analogous to those observed in earlier work on Ni(II) in mixtures of KCl and ZnCl2.

Original languageEnglish (US)
Pages (from-to)2243-2247
Number of pages5
JournalJournal of Inorganic and Nuclear Chemistry
Volume29
Issue number9
StatePublished - Sep 1967
Externally publishedYes

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zinc chlorides
aluminum chlorides
Zinc chloride
Aluminum chloride
Cobalt
Molten materials
cobalt
Absorption spectra
absorption spectra
Chemical analysis
Temperature
temperature
zinc chloride
aluminum chloride

Cite this

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title = "Octahedral and tetrahedral co-ordination states of cobalt (II) in molten zinc chloride-aluminium chloride mixtures",
abstract = "Absorption spectra of Co(II) have been studied in molten mixtures of ZnCl2 and AlCl3 both as a function of melt composition and of temperature. The spectral changes have been interpreted in terms of an octahedral-tetrahedral equilibrium involving chloro-complexes of Co(II), analogous to those observed in earlier work on Ni(II) in mixtures of KCl and ZnCl2.",
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T1 - Octahedral and tetrahedral co-ordination states of cobalt (II) in molten zinc chloride-aluminium chloride mixtures

AU - Angell, Charles

AU - Gruen, D. M.

PY - 1967/9

Y1 - 1967/9

N2 - Absorption spectra of Co(II) have been studied in molten mixtures of ZnCl2 and AlCl3 both as a function of melt composition and of temperature. The spectral changes have been interpreted in terms of an octahedral-tetrahedral equilibrium involving chloro-complexes of Co(II), analogous to those observed in earlier work on Ni(II) in mixtures of KCl and ZnCl2.

AB - Absorption spectra of Co(II) have been studied in molten mixtures of ZnCl2 and AlCl3 both as a function of melt composition and of temperature. The spectral changes have been interpreted in terms of an octahedral-tetrahedral equilibrium involving chloro-complexes of Co(II), analogous to those observed in earlier work on Ni(II) in mixtures of KCl and ZnCl2.

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M3 - Article

VL - 29

SP - 2243

EP - 2247

JO - Polyhedron

JF - Polyhedron

SN - 0277-5387

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