Observation of dynamic nanostructural and nanochemical changes in ceria-based catalysts during in-situ reduction

R. Sharma, Peter Crozier, Z. C. Kang, L. Eyring

Research output: Contribution to journalArticle

62 Scopus citations

Abstract

We have studied the nanostructural and nanochemical changes occurring in pure ceria (CeC2) and CeO2-zirconia (ZrO2) catalysts during reduction. The reduction is carried out in an environmental transmission electron microscope in dry H2 at 2 Torr up to 800°C. We use in-situ electron-energy-loss spectroscopy to follow changes in the oxidation state of the Ce at close to the nanometre level. Our measurements show that reduction may or may not be accompanied by significant structural rearrangements in the material. In pure CeO2 and the mixed oxide, the reduced form can be composed of both crystalline and amorphous material. Our measurements confirm the formation of a superlattice formed due to the ordering of O vacancies in CeO2 during reduction. The mixed oxide material shows that O vacancy ordering occurs only over 2-3 nm domains.

Original languageEnglish (US)
Pages (from-to)2731-2747
Number of pages17
JournalPhilosophical Magazine
Volume84
Issue number25-26
DOIs
StatePublished - Sep 1 2004

ASJC Scopus subject areas

  • Condensed Matter Physics

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