Non-Condon theory of nonadiabatic electron transfer reactions in V-shaped donor-bridge-acceptor complexes

Anatoli Milischuk; Dmitry Matyushov

doi:10.1063/1.1555635

Non-Condon theory of nonadiabatic electron transfer reactions in V-shaped donor-bridge-acceptor complexes

Anatoli Milischuk, Dmitry Matyushov

Molecular Sciences, School of (SMS)

Research output: Contribution to journal › Article › peer-review

14 Scopus citations

Abstract

Possibilities for an effective alteration of the electron transfer (ET) matrix element in bent donor-bridge-acceptor (DBA) molecules were explored. It was demonstrated that certain donor-acceptor (DA) energy gaps result in zero longitudinal projections of the adiabatic transition dipole and, therefore H_ET=0.

Original language	English (US)
Pages (from-to)	5596-5606
Number of pages	11
Journal	Journal of Chemical Physics
Volume	118
Issue number	12
DOIs	https://doi.org/10.1063/1.1555635
State	Published - Mar 22 2003

ASJC Scopus subject areas

General Physics and Astronomy
Physical and Theoretical Chemistry

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title = "Non-Condon theory of nonadiabatic electron transfer reactions in V-shaped donor-bridge-acceptor complexes",

abstract = "Possibilities for an effective alteration of the electron transfer (ET) matrix element in bent donor-bridge-acceptor (DBA) molecules were explored. It was demonstrated that certain donor-acceptor (DA) energy gaps result in zero longitudinal projections of the adiabatic transition dipole and, therefore HET=0.",

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AU - Milischuk, Anatoli

AU - Matyushov, Dmitry

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N2 - Possibilities for an effective alteration of the electron transfer (ET) matrix element in bent donor-bridge-acceptor (DBA) molecules were explored. It was demonstrated that certain donor-acceptor (DA) energy gaps result in zero longitudinal projections of the adiabatic transition dipole and, therefore HET=0.

AB - Possibilities for an effective alteration of the electron transfer (ET) matrix element in bent donor-bridge-acceptor (DBA) molecules were explored. It was demonstrated that certain donor-acceptor (DA) energy gaps result in zero longitudinal projections of the adiabatic transition dipole and, therefore HET=0.

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Non-Condon theory of nonadiabatic electron transfer reactions in V-shaped donor-bridge-acceptor complexes

Abstract

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