Non-Condon theory of nonadiabatic electron transfer reactions in V-shaped donor-bridge-acceptor complexes

Anatoli Milischuk, Dmitry Matyushov

Research output: Contribution to journalArticlepeer-review

14 Scopus citations

Abstract

Possibilities for an effective alteration of the electron transfer (ET) matrix element in bent donor-bridge-acceptor (DBA) molecules were explored. It was demonstrated that certain donor-acceptor (DA) energy gaps result in zero longitudinal projections of the adiabatic transition dipole and, therefore HET=0.

Original languageEnglish (US)
Pages (from-to)5596-5606
Number of pages11
JournalJournal of Chemical Physics
Volume118
Issue number12
DOIs
StatePublished - Mar 22 2003

ASJC Scopus subject areas

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

Fingerprint Dive into the research topics of 'Non-Condon theory of nonadiabatic electron transfer reactions in V-shaped donor-bridge-acceptor complexes'. Together they form a unique fingerprint.

Cite this