Nitrogen incorporation in silicates and metals

Results from SIMS, EPMA, FTIR, and laser-extraction mass spectrometry

Jed L. Mosenfelder, Anette Von Der Handt, Evelyn Füri, Celia Dalou, Richard Hervig, George R. Rossman, Marc M. Hirschmann

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

A quantitative understanding of nitrogen incorporation in Earth materials is important for constraining volatile evolution in planetary bodies. We used a combination of chemical (SIMS, EPMA, and laser-extraction mass spectrometry) and spectroscopic (FTIR) observations to study nitrogen contents and speciation mechanisms in silicate glasses, metal alloys, and an N-bearing silicate mineral (hyalophane). One suite of Fe-free basaltic glasses was studied by all four methods. Concentrations of N in these glasses determined by EPMA are systematically higher than those measured by laser extraction but agree within mutual 2s uncertainties, demonstrating the general veracity of the EPMA method. SIMS working curves based on measurement of 14N+ and 14N16O- as a function of N content determined by EPMA (or laser extraction) are best fit with exponential functions rather than the linear regressions that are most commonly applied to SIMS data. On the other hand, the relationship based on 12C14N- for C-poor, Fe-free glasses is exceptionally well fit to a linear regression (r2 = 1, p < 0.001), in contrast to expectations from previous work on glasses with lower N contents. Matrix effects on the SIMS signals associated with Fe or H2O content are not justified by the data, but volatile data (both N and H) for hyalophane, which contains 20 wt% BaO, reveal matrix effects possibly induced by its high average molar mass. A combination of FTIR and chemical data, together with a thorough review of the literature, was used to determine incorporation mechanisms for N in the Fe-free glasses. We infer that under reducing conditions at high pressure and temperature N is dissolved in basaltic melts chiefly as NH2 and NH2-, with N2 and/or nitride (X-N3-) complexes 2 becoming increasingly important at low fO2, increasing N content, and decreasing H content. Our results have implications for future studies seeking to accurately measure N by SIMS and for studies of N partitioning at high pressure relevant to planetary accretion and differentiation.

Original languageEnglish (US)
Pages (from-to)31-46
Number of pages16
JournalAmerican Mineralogist
Volume104
Issue number1
DOIs
StatePublished - Jan 1 2019

Fingerprint

Silicates
Electron probe microanalysis
Secondary ion mass spectrometry
secondary ion mass spectrometry
Mass spectrometry
silicates
Nitrogen
mass spectroscopy
silicate
mass spectrometry
laser
glass
Metals
nitrogen
Glass
Lasers
metal
metals
lasers
Linear regression

Keywords

  • bonding
  • carbon
  • EPMA
  • FTIR
  • nitrogen
  • SIMS
  • speciation

ASJC Scopus subject areas

  • Geophysics
  • Geochemistry and Petrology

Cite this

Nitrogen incorporation in silicates and metals : Results from SIMS, EPMA, FTIR, and laser-extraction mass spectrometry. / Mosenfelder, Jed L.; Handt, Anette Von Der; Füri, Evelyn; Dalou, Celia; Hervig, Richard; Rossman, George R.; Hirschmann, Marc M.

In: American Mineralogist, Vol. 104, No. 1, 01.01.2019, p. 31-46.

Research output: Contribution to journalArticle

Mosenfelder, Jed L. ; Handt, Anette Von Der ; Füri, Evelyn ; Dalou, Celia ; Hervig, Richard ; Rossman, George R. ; Hirschmann, Marc M. / Nitrogen incorporation in silicates and metals : Results from SIMS, EPMA, FTIR, and laser-extraction mass spectrometry. In: American Mineralogist. 2019 ; Vol. 104, No. 1. pp. 31-46.
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