TY - JOUR
T1 - Nitric oxide complexes of iron(II) and iron(III) porphyrins
AU - Wayland, Bradford B.
AU - Olson, Larry W.
N1 - Funding Information:
We acknowledge support of the National Science Foundation. FIGURE.E.s.r. spectra for FeII(TPP)NO in toluene. (a)-140 "C (g, = 2.103, A, = 12.6 G; g, = 2.064, A, = 17.2 G; g, = 2.010, A, = 17-3G). (b) Room temperature ((g') = 2.051, (A) = 16.3 G). (Received, 25th July 1973; Cow. 1079.) 1 D. V. Stynes and B. R. James, J.C.S. Chem. Comm.,, 1973, 325; J. P. Collman and C. A. Reed, J. Amer. Chem. SOL, 1973,95,2048; B. B. Wayland, J. Minkiewicz, and M. E. Abd-Elmageed, J. Amer. Chem. SOC., submitted for publication. 2 E. B. Fleischer and T. S. Srivastava, J. Amer. Chem. SOC., 1969, 91, 2403. 8 T. Yonetani, H. Yamamoto, J. E. Erman, J. S. Leigh, jun., and G. H. Reed, J. Biol. Chem., 1972, 247, 2447, 4 E. Antonini and M. Brunori, 'Hemoglobin and Myoglobin in their Reactions with Ligands,' North-Holland, Amsterdam, 1971. 5 L. Vaska and H. Nakai, J. Amer. Chem. SOC., 1973, 6431. "D. V. Stynes, H. C. Stynes, B. R. James, and J. A. Ibers, J. Amer. Chem. SOG.,1973, 95, 2047. J. C. W. Chien, J. Cheun. Phys., 1969,51,4220. 8 H. Kon and N. Kataoka, Biochemistry, 1969, 8, 4747. S L. C. Dickinson and J. C. W. Chien, J. Amer. Chem. SOC., 1971, 93, 5036. 10 J. C. W. Chien, J. Amer. Chem. SOC.,1969,91, 2166.
PY - 1973
Y1 - 1973
N2 - The reversible formation of a nitric oxide adduct with tetraphenylporphyriniron(III) chloride formulated as [FeII(TPP) Cl-NO+] is observed in toluene, but reductive nitrosylation to give FeII(TPP)·NO occurs in the presence of a hydroxylic solvent, in reactions analogous to hemeprotein interactions with nitric oxide.
AB - The reversible formation of a nitric oxide adduct with tetraphenylporphyriniron(III) chloride formulated as [FeII(TPP) Cl-NO+] is observed in toluene, but reductive nitrosylation to give FeII(TPP)·NO occurs in the presence of a hydroxylic solvent, in reactions analogous to hemeprotein interactions with nitric oxide.
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U2 - 10.1039/C39730000897
DO - 10.1039/C39730000897
M3 - Article
AN - SCOPUS:37049142100
SN - 0577-6171
SP - 897
EP - 898
JO - Journal of the Chemical Society D: Chemical Communications
JF - Journal of the Chemical Society D: Chemical Communications
IS - 23
ER -