The reversible formation of a nitric oxide adduct with tetraphenylporphyriniron(III) chloride formulated as [FeII(TPP) Cl-NO+] is observed in toluene, but reductive nitrosylation to give FeII(TPP)·NO occurs in the presence of a hydroxylic solvent, in reactions analogous to hemeprotein interactions with nitric oxide.
|Original language||English (US)|
|Number of pages||2|
|Journal||Journal of the Chemical Society, Chemical Communications|
|State||Published - 1973|
ASJC Scopus subject areas
- Molecular Medicine