Nitric oxide complexes of iron(II) and iron(III) porphyrins

Bradford B. Wayland, Larry W. Olson

Research output: Contribution to journalArticlepeer-review

52 Scopus citations

Abstract

The reversible formation of a nitric oxide adduct with tetraphenylporphyriniron(III) chloride formulated as [FeII(TPP) Cl-NO+] is observed in toluene, but reductive nitrosylation to give FeII(TPP)·NO occurs in the presence of a hydroxylic solvent, in reactions analogous to hemeprotein interactions with nitric oxide.

Original languageEnglish (US)
Pages (from-to)897-898
Number of pages2
JournalJournal of the Chemical Society, Chemical Communications
Issue number23
DOIs
StatePublished - Dec 1 1973
Externally publishedYes

ASJC Scopus subject areas

  • Molecular Medicine

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