Nitric oxide complexes of iron(II) and iron(III) porphyrins

Bradford B. Wayland, Larry Olson

Research output: Contribution to journalArticle

52 Citations (Scopus)

Abstract

The reversible formation of a nitric oxide adduct with tetraphenylporphyriniron(III) chloride formulated as [FeII(TPP) Cl-NO+] is observed in toluene, but reductive nitrosylation to give FeII(TPP)·NO occurs in the presence of a hydroxylic solvent, in reactions analogous to hemeprotein interactions with nitric oxide.

Original languageEnglish (US)
Pages (from-to)897-898
Number of pages2
JournalJournal of the Chemical Society, Chemical Communications
Issue number23
DOIs
StatePublished - 1973
Externally publishedYes

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Porphyrins
Nitric Oxide
Iron
Hemeproteins
Toluene
Chlorides

ASJC Scopus subject areas

  • Molecular Medicine

Cite this

Nitric oxide complexes of iron(II) and iron(III) porphyrins. / Wayland, Bradford B.; Olson, Larry.

In: Journal of the Chemical Society, Chemical Communications, No. 23, 1973, p. 897-898.

Research output: Contribution to journalArticle

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abstract = "The reversible formation of a nitric oxide adduct with tetraphenylporphyriniron(III) chloride formulated as [FeII(TPP) Cl-NO+] is observed in toluene, but reductive nitrosylation to give FeII(TPP)·NO occurs in the presence of a hydroxylic solvent, in reactions analogous to hemeprotein interactions with nitric oxide.",
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