Nanostructure of electrically conducting polyaniline prepared by a novel emulsion polymerization process

Jingyue Liu, P. J. Kinlen, C. R. Graham

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Abstract

A soluble polyaniline (PANI) salt with moderate conductivity was synthesized by a novel emulsion polymerization process. The conductivity of the processed PANI films can be substantially increased by treating the polymer films with surfactants or with low molecular weight alcohols. Transmission electron microscopy (TEM) images of thin polymer films revealed the existence of small islands of conducting PANI embedded in a non-conducting, dopant matrix. The conductivity of the PANI films is affected by the spatial distribution and the connectivity of these small islands. The conductivity enhancement observed upon treatment with surfactants is due to self-assembly of conducting PANI molecules into an interconnected network morphology. In the case of alcohol treatment the film conductivity is enhanced due to extraction of excess dopant phase and the subsequent densification of PANI islands to form highly conducting pathways.

Original languageEnglish (US)
Title of host publicationMaterials Research Society Symposium - Proceedings
EditorsJ.R. Reynolds, A.K.Y. Jen, M.F. Rubner, L.Y. Chiang, L.R. Dalton
PublisherMRS
Pages623-628
Number of pages6
Volume488
StatePublished - 1997
Externally publishedYes
EventProceedings of the 1997 MRS Fall Meeting - Boston, MA, USA
Duration: Dec 1 1997Dec 5 1997

Other

OtherProceedings of the 1997 MRS Fall Meeting
CityBoston, MA, USA
Period12/1/9712/5/97

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials

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  • Cite this

    Liu, J., Kinlen, P. J., & Graham, C. R. (1997). Nanostructure of electrically conducting polyaniline prepared by a novel emulsion polymerization process. In J. R. Reynolds, A. K. Y. Jen, M. F. Rubner, L. Y. Chiang, & L. R. Dalton (Eds.), Materials Research Society Symposium - Proceedings (Vol. 488, pp. 623-628). MRS.