Multiple-inclusion model for the transport properties of porous composites considering coupled effects of pores and interphase around spheroidal particles

Wenxiang Xu, Dongyang Zhang, Peng Lan, Yang Jiao

Research output: Contribution to journalArticle

Abstract

Understanding of the effects of particle geometries, pores and interphase characteristics on transport properties of porous composites is very crucial to the smart design of porous composites and the improvement of their durability. In this work, the authors devise a multiple-inclusion micromechanical model to predict the effective transport properties of multiphase porous composites, where spheroidal inclusions of diverse types are randomly dispersed in a homogeneous matrix. The multiple-inclusion model is then applied to estimate the effective diffusivity of four-phase porous composites containing impermeable particles, pores, highly permeable interphase and matrix. Specifically, the microstructural characteristics of pores, interphase and particles, and their physical properties are incorporated into the evaluation of the effective diffusivity of porous composites. It is shown that the present model leads the prediction of diffusivity of porous composites to reasonable accuracy by comparing with extensive experimental data. Moreover, utilizing the proposed model, we investigate the dependence of effective diffusivity of porous composites on the shape, volume fraction and size distribution of impermeable particles, the interphase thickness and volume fraction, and the porosity characterized by the hydration degree of cement and the water-cement ratio. The results reveal that the geometrical and physical properties of these components play a significant role in determining the diffusivity of porous composites. The multiple-inclusion model provides a powerful and convenient predictive toolkit for multiphase composite design and evaluation.

LanguageEnglish (US)
Pages610-616
Number of pages7
JournalInternational Journal of Mechanical Sciences
Volume150
DOIs
StatePublished - Jan 1 2019

Fingerprint

Transport properties
transport properties
inclusions
porosity
composite materials
Composite materials
diffusivity
cements
Volume fraction
Cements
Physical properties
physical properties
evaluation
matrices
durability
Hydration
hydration
Durability
Porosity
Geometry

Keywords

  • Diffusivity
  • Interphase
  • Multiple inclusions
  • Pore
  • Porous composites
  • Spheroidal particle

ASJC Scopus subject areas

  • Civil and Structural Engineering
  • Materials Science(all)
  • Condensed Matter Physics
  • Mechanics of Materials
  • Mechanical Engineering

Cite this

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title = "Multiple-inclusion model for the transport properties of porous composites considering coupled effects of pores and interphase around spheroidal particles",
abstract = "Understanding of the effects of particle geometries, pores and interphase characteristics on transport properties of porous composites is very crucial to the smart design of porous composites and the improvement of their durability. In this work, the authors devise a multiple-inclusion micromechanical model to predict the effective transport properties of multiphase porous composites, where spheroidal inclusions of diverse types are randomly dispersed in a homogeneous matrix. The multiple-inclusion model is then applied to estimate the effective diffusivity of four-phase porous composites containing impermeable particles, pores, highly permeable interphase and matrix. Specifically, the microstructural characteristics of pores, interphase and particles, and their physical properties are incorporated into the evaluation of the effective diffusivity of porous composites. It is shown that the present model leads the prediction of diffusivity of porous composites to reasonable accuracy by comparing with extensive experimental data. Moreover, utilizing the proposed model, we investigate the dependence of effective diffusivity of porous composites on the shape, volume fraction and size distribution of impermeable particles, the interphase thickness and volume fraction, and the porosity characterized by the hydration degree of cement and the water-cement ratio. The results reveal that the geometrical and physical properties of these components play a significant role in determining the diffusivity of porous composites. The multiple-inclusion model provides a powerful and convenient predictive toolkit for multiphase composite design and evaluation.",
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author = "Wenxiang Xu and Dongyang Zhang and Peng Lan and Yang Jiao",
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AU - Zhang, Dongyang

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AU - Jiao, Yang

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AB - Understanding of the effects of particle geometries, pores and interphase characteristics on transport properties of porous composites is very crucial to the smart design of porous composites and the improvement of their durability. In this work, the authors devise a multiple-inclusion micromechanical model to predict the effective transport properties of multiphase porous composites, where spheroidal inclusions of diverse types are randomly dispersed in a homogeneous matrix. The multiple-inclusion model is then applied to estimate the effective diffusivity of four-phase porous composites containing impermeable particles, pores, highly permeable interphase and matrix. Specifically, the microstructural characteristics of pores, interphase and particles, and their physical properties are incorporated into the evaluation of the effective diffusivity of porous composites. It is shown that the present model leads the prediction of diffusivity of porous composites to reasonable accuracy by comparing with extensive experimental data. Moreover, utilizing the proposed model, we investigate the dependence of effective diffusivity of porous composites on the shape, volume fraction and size distribution of impermeable particles, the interphase thickness and volume fraction, and the porosity characterized by the hydration degree of cement and the water-cement ratio. The results reveal that the geometrical and physical properties of these components play a significant role in determining the diffusivity of porous composites. The multiple-inclusion model provides a powerful and convenient predictive toolkit for multiphase composite design and evaluation.

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