Multiple hydrogen bonding for the noncovalent attachment of ionic functionality in triblock copolymers

Brian D. Mather; Margaux B. Baker; Frederick L. Beyer; Matthew D. Green; Michael A.G. Berg; Timothy E. Long

doi:10.1021/ma070102a

Multiple hydrogen bonding for the noncovalent attachment of ionic functionality in triblock copolymers

Brian D. Mather, Margaux B. Baker, Frederick L. Beyer, Matthew D. Green, Michael A.G. Berg, Timothy E. Long

Research output: Contribution to journal › Article › peer-review

43 Scopus citations

Abstract

A study was conducted to define a new strategy for the introduction of thermally stable ionic sites to block copolymers through hydrogen bonding. Hydrogen bonding exhibited lower enthalpies and greater specificity, which enabled molecular recognition and lower melt viscosities, using hydrogen-bonding arrays, such as ureido pyrimidones (UPy) and nucleobase pairs. Novel hydrogen-bonding triblock copolymers containing adenine, were synthesized through nitroxide-mediated polymerization. A novel difunctional initiator, which does not introduce hydrolytically unstable ester links that lead to molecular weight loss, permitted the formation of symmetric outer blocks, reduced the number of monomer additions, and enabled a single crossover reaction.

Original language	English (US)
Pages (from-to)	4396-4398
Number of pages	3
Journal	Macromolecules
Volume	40
Issue number	13
DOIs	https://doi.org/10.1021/ma070102a
State	Published - Jun 26 2007
Externally published	Yes

ASJC Scopus subject areas

Organic Chemistry
Polymers and Plastics
Inorganic Chemistry
Materials Chemistry

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abstract = "A study was conducted to define a new strategy for the introduction of thermally stable ionic sites to block copolymers through hydrogen bonding. Hydrogen bonding exhibited lower enthalpies and greater specificity, which enabled molecular recognition and lower melt viscosities, using hydrogen-bonding arrays, such as ureido pyrimidones (UPy) and nucleobase pairs. Novel hydrogen-bonding triblock copolymers containing adenine, were synthesized through nitroxide-mediated polymerization. A novel difunctional initiator, which does not introduce hydrolytically unstable ester links that lead to molecular weight loss, permitted the formation of symmetric outer blocks, reduced the number of monomer additions, and enabled a single crossover reaction.",

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AU - Mather, Brian D.

AU - Baker, Margaux B.

AU - Beyer, Frederick L.

AU - Green, Matthew D.

AU - Berg, Michael A.G.

AU - Long, Timothy E.

PY - 2007/6/26

Y1 - 2007/6/26

N2 - A study was conducted to define a new strategy for the introduction of thermally stable ionic sites to block copolymers through hydrogen bonding. Hydrogen bonding exhibited lower enthalpies and greater specificity, which enabled molecular recognition and lower melt viscosities, using hydrogen-bonding arrays, such as ureido pyrimidones (UPy) and nucleobase pairs. Novel hydrogen-bonding triblock copolymers containing adenine, were synthesized through nitroxide-mediated polymerization. A novel difunctional initiator, which does not introduce hydrolytically unstable ester links that lead to molecular weight loss, permitted the formation of symmetric outer blocks, reduced the number of monomer additions, and enabled a single crossover reaction.

AB - A study was conducted to define a new strategy for the introduction of thermally stable ionic sites to block copolymers through hydrogen bonding. Hydrogen bonding exhibited lower enthalpies and greater specificity, which enabled molecular recognition and lower melt viscosities, using hydrogen-bonding arrays, such as ureido pyrimidones (UPy) and nucleobase pairs. Novel hydrogen-bonding triblock copolymers containing adenine, were synthesized through nitroxide-mediated polymerization. A novel difunctional initiator, which does not introduce hydrolytically unstable ester links that lead to molecular weight loss, permitted the formation of symmetric outer blocks, reduced the number of monomer additions, and enabled a single crossover reaction.

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Multiple hydrogen bonding for the noncovalent attachment of ionic functionality in triblock copolymers

Abstract

ASJC Scopus subject areas

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