Multipetal-Structured and Dumbbell-Structured Gold-Polymer Composite Particles with Self-Modulated Catalytic Activity

Mingmeng Zhang, Todd P. Otanicar, Patrick Phelan, Lenore Dai

Research output: Contribution to journalArticle

1 Citation (Scopus)

Abstract

A simple synthesis route for gold-polymer composite particles with controlled structure (multipetal structure and dumbbell structure) is developed. It is intriguing to observe that by controlling the reaction time and size of gold nanoparticles (AuNPs), tetrapetal-, tripetal-, and dumbbell-structured gold-polystyrene composite are obtained via seeded polymerization. The average number of petals on a single AuNP increases with the AuNP diameter. These particles show potential applications as building blocks for advanced ordered and hierarchical supracolloidal materials. Further, with the incorporation of poly(N-isopropylacrylamide) (PNIPAm), "smart" thermoresponsive dumbbell-structured gold-PNIPAm/polystyrene composite particles are formed. Significant size variation is validated for particles with 83 and 91 wt % PNIPAm content around lower critical solution temperature (LCST), which results in self-modulated catalytic activity.

Original languageEnglish (US)
Pages (from-to)13191-13200
Number of pages10
JournalLangmuir
Volume31
Issue number48
DOIs
StatePublished - Oct 7 2015

Fingerprint

Gold
catalytic activity
Catalyst activity
Polymers
gold
composite materials
Polystyrenes
Composite materials
polymers
polystyrene
petals
reaction time
polymerization
routes
Polymerization
Nanoparticles
nanoparticles
synthesis
poly-N-isopropylacrylamide
Temperature

ASJC Scopus subject areas

  • Electrochemistry
  • Condensed Matter Physics
  • Surfaces and Interfaces
  • Materials Science(all)
  • Spectroscopy

Cite this

Multipetal-Structured and Dumbbell-Structured Gold-Polymer Composite Particles with Self-Modulated Catalytic Activity. / Zhang, Mingmeng; Otanicar, Todd P.; Phelan, Patrick; Dai, Lenore.

In: Langmuir, Vol. 31, No. 48, 07.10.2015, p. 13191-13200.

Research output: Contribution to journalArticle

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