Molecular beam optical Zeeman spectroscopy of iridium mononitride

Timothy Steimle; A. J. Marr; S. A. Beaton; J. M. Brown

doi:10.1063/1.473141

Molecular beam optical Zeeman spectroscopy of iridium mononitride

Timothy Steimle, A. J. Marr, S. A. Beaton, J. M. Brown

Molecular Sciences, School of (SMS)

Research output: Contribution to journal › Article › peer-review

12 Scopus citations

Abstract

The Zeeman effect on the F-1/2←3/2 hyperfine component of the R(0) line in the (0,0) band of the A¹Π-X¹Σ⁺ transition of iridium mononitride, IrN, was investigated using a supersonic molecular beam optical spectrometer. The magnetic g_J-factor for IrN in the A¹Π state was determined to be 0.96±0.05. The general applicability of Zeeman measurements is described and the g_J-factor which is determined is related to plausible molecular orbital descriptions for IrN in the A¹Π state.

Original language	English (US)
Pages (from-to)	2073-2077
Number of pages	5
Journal	Journal of Chemical Physics
Volume	106
Issue number	6
DOIs	https://doi.org/10.1063/1.473141
State	Published - Feb 8 1997

ASJC Scopus subject areas

General Physics and Astronomy
Physical and Theoretical Chemistry

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title = "Molecular beam optical Zeeman spectroscopy of iridium mononitride",

abstract = "The Zeeman effect on the F-1/2←3/2 hyperfine component of the R(0) line in the (0,0) band of the A1Π-X1Σ+ transition of iridium mononitride, IrN, was investigated using a supersonic molecular beam optical spectrometer. The magnetic gJ-factor for IrN in the A1Π state was determined to be 0.96±0.05. The general applicability of Zeeman measurements is described and the gJ-factor which is determined is related to plausible molecular orbital descriptions for IrN in the A1Π state.",

author = "Timothy Steimle and Marr, {A. J.} and Beaton, {S. A.} and Brown, {J. M.}",

year = "1997",

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T1 - Molecular beam optical Zeeman spectroscopy of iridium mononitride

AU - Steimle, Timothy

AU - Marr, A. J.

AU - Beaton, S. A.

AU - Brown, J. M.

PY - 1997/2/8

Y1 - 1997/2/8

N2 - The Zeeman effect on the F-1/2←3/2 hyperfine component of the R(0) line in the (0,0) band of the A1Π-X1Σ+ transition of iridium mononitride, IrN, was investigated using a supersonic molecular beam optical spectrometer. The magnetic gJ-factor for IrN in the A1Π state was determined to be 0.96±0.05. The general applicability of Zeeman measurements is described and the gJ-factor which is determined is related to plausible molecular orbital descriptions for IrN in the A1Π state.

AB - The Zeeman effect on the F-1/2←3/2 hyperfine component of the R(0) line in the (0,0) band of the A1Π-X1Σ+ transition of iridium mononitride, IrN, was investigated using a supersonic molecular beam optical spectrometer. The magnetic gJ-factor for IrN in the A1Π state was determined to be 0.96±0.05. The general applicability of Zeeman measurements is described and the gJ-factor which is determined is related to plausible molecular orbital descriptions for IrN in the A1Π state.

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U2 - 10.1063/1.473141

DO - 10.1063/1.473141

M3 - Article

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SN - 0021-9606

VL - 106

SP - 2073

EP - 2077

JO - Journal of Chemical Physics

JF - Journal of Chemical Physics

IS - 6

ER -

Molecular beam optical Zeeman spectroscopy of iridium mononitride

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