Abstract

This research used temperature-programmed reaction spectroscopy (TPRS) in UHV to probe the chemistry of titania-modified, alumina-modified and oxygen-modified Ni surfaces. Formic acid decomposition was chosen as the probe reaction because the decomposition activation energy has been shown to be dependent on the support for support Ni crystallites, and because the activation energy and reaction mechanism have been shown to be dependent on the chemical state of the metal surface for Ni single crystals.

Original languageEnglish (US)
Title of host publicationAmerican Chemical Society, Division of Petroleum Chemistry, Preprints
EditorsW.E. Haines
PublisherACS
Pages214-218
Number of pages5
Volume31
Edition1
StatePublished - Mar 1986

Fingerprint

Formic acid
Alumina
Activation energy
Titanium
Nickel
Decomposition
Oxygen
Crystallites
Chemical activation
Single crystals
Spectroscopy
Metals
Temperature

ASJC Scopus subject areas

  • Fuel Technology

Cite this

Raupp, G., & Dumesic, J. A. (1986). MODIFICATION OF FORMIC ACID DECOMPOSITION OVER NICKEL BY OXYGEN, TITANIA AND ALUMINA ADLAYERS. In W. E. Haines (Ed.), American Chemical Society, Division of Petroleum Chemistry, Preprints (1 ed., Vol. 31, pp. 214-218). ACS.

MODIFICATION OF FORMIC ACID DECOMPOSITION OVER NICKEL BY OXYGEN, TITANIA AND ALUMINA ADLAYERS. / Raupp, Gregory; Dumesic, J. A.

American Chemical Society, Division of Petroleum Chemistry, Preprints. ed. / W.E. Haines. Vol. 31 1. ed. ACS, 1986. p. 214-218.

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Raupp, G & Dumesic, JA 1986, MODIFICATION OF FORMIC ACID DECOMPOSITION OVER NICKEL BY OXYGEN, TITANIA AND ALUMINA ADLAYERS. in WE Haines (ed.), American Chemical Society, Division of Petroleum Chemistry, Preprints. 1 edn, vol. 31, ACS, pp. 214-218.
Raupp G, Dumesic JA. MODIFICATION OF FORMIC ACID DECOMPOSITION OVER NICKEL BY OXYGEN, TITANIA AND ALUMINA ADLAYERS. In Haines WE, editor, American Chemical Society, Division of Petroleum Chemistry, Preprints. 1 ed. Vol. 31. ACS. 1986. p. 214-218
Raupp, Gregory ; Dumesic, J. A. / MODIFICATION OF FORMIC ACID DECOMPOSITION OVER NICKEL BY OXYGEN, TITANIA AND ALUMINA ADLAYERS. American Chemical Society, Division of Petroleum Chemistry, Preprints. editor / W.E. Haines. Vol. 31 1. ed. ACS, 1986. pp. 214-218
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