MODIFICATION OF FORMIC ACID DECOMPOSITION OVER NICKEL BY OXYGEN, TITANIA AND ALUMINA ADLAYERS.

Gregory Raupp; J. A. Dumesic

MODIFICATION OF FORMIC ACID DECOMPOSITION OVER NICKEL BY OXYGEN, TITANIA AND ALUMINA ADLAYERS.

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution

Abstract

This research used temperature-programmed reaction spectroscopy (TPRS) in UHV to probe the chemistry of titania-modified, alumina-modified and oxygen-modified Ni surfaces. Formic acid decomposition was chosen as the probe reaction because the decomposition activation energy has been shown to be dependent on the support for support Ni crystallites, and because the activation energy and reaction mechanism have been shown to be dependent on the chemical state of the metal surface for Ni single crystals.

Original language	English (US)
Title of host publication	American Chemical Society, Division of Petroleum Chemistry, Preprints
Editors	W.E. Haines
Publisher	ACS
Pages	214-218
Number of pages	5
Volume	31
Edition	1
State	Published - Mar 1986

ASJC Scopus subject areas

Fuel Technology

Cite this

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title = "MODIFICATION OF FORMIC ACID DECOMPOSITION OVER NICKEL BY OXYGEN, TITANIA AND ALUMINA ADLAYERS.",

abstract = "This research used temperature-programmed reaction spectroscopy (TPRS) in UHV to probe the chemistry of titania-modified, alumina-modified and oxygen-modified Ni surfaces. Formic acid decomposition was chosen as the probe reaction because the decomposition activation energy has been shown to be dependent on the support for support Ni crystallites, and because the activation energy and reaction mechanism have been shown to be dependent on the chemical state of the metal surface for Ni single crystals.",

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N2 - This research used temperature-programmed reaction spectroscopy (TPRS) in UHV to probe the chemistry of titania-modified, alumina-modified and oxygen-modified Ni surfaces. Formic acid decomposition was chosen as the probe reaction because the decomposition activation energy has been shown to be dependent on the support for support Ni crystallites, and because the activation energy and reaction mechanism have been shown to be dependent on the chemical state of the metal surface for Ni single crystals.

AB - This research used temperature-programmed reaction spectroscopy (TPRS) in UHV to probe the chemistry of titania-modified, alumina-modified and oxygen-modified Ni surfaces. Formic acid decomposition was chosen as the probe reaction because the decomposition activation energy has been shown to be dependent on the support for support Ni crystallites, and because the activation energy and reaction mechanism have been shown to be dependent on the chemical state of the metal surface for Ni single crystals.

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ER -

MODIFICATION OF FORMIC ACID DECOMPOSITION OVER NICKEL BY OXYGEN, TITANIA AND ALUMINA ADLAYERS.

Abstract

ASJC Scopus subject areas

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