Mechanistic Studies of the Photodecomposition of Arylmethyl Sulfones in Homogeneous and Micellar Solutions

Ian R. Gould; Chen ho Tung; Nicholas J. Turro; Richard S. Givens; Bogdan Matuszewski

doi:10.1021/ja00318a038

Mechanistic Studies of the Photodecomposition of Arylmethyl Sulfones in Homogeneous and Micellar Solutions

Ian R. Gould, Chen ho Tung, Nicholas J. Turro, Richard S. Givens, Bogdan Matuszewski

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33 Scopus citations

Abstract

The mechanism of photodecomposition of aryl sulfones has been investigated by using both steady-state and time-resolved techniques. Direct evidence for radical and triplet-state intermediates is provided. A correlation is found between the dynamics of reaction of the intermediate triplet states with the stabilities of the intermediate radicals.

Original language	English (US)
Pages (from-to)	1789-1793
Number of pages	5
Journal	Journal of the American Chemical Society
Volume	106
Issue number	6
DOIs	https://doi.org/10.1021/ja00318a038
State	Published - Mar 1 1984
Externally published	Yes

ASJC Scopus subject areas

Catalysis
General Chemistry
Biochemistry
Colloid and Surface Chemistry

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title = "Mechanistic Studies of the Photodecomposition of Arylmethyl Sulfones in Homogeneous and Micellar Solutions",

abstract = "The mechanism of photodecomposition of aryl sulfones has been investigated by using both steady-state and time-resolved techniques. Direct evidence for radical and triplet-state intermediates is provided. A correlation is found between the dynamics of reaction of the intermediate triplet states with the stabilities of the intermediate radicals.",

author = "Gould, {Ian R.} and Tung, {Chen ho} and Turro, {Nicholas J.} and Givens, {Richard S.} and Bogdan Matuszewski",

year = "1984",

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T1 - Mechanistic Studies of the Photodecomposition of Arylmethyl Sulfones in Homogeneous and Micellar Solutions

AU - Gould, Ian R.

AU - Tung, Chen ho

AU - Turro, Nicholas J.

AU - Givens, Richard S.

AU - Matuszewski, Bogdan

PY - 1984/3/1

Y1 - 1984/3/1

N2 - The mechanism of photodecomposition of aryl sulfones has been investigated by using both steady-state and time-resolved techniques. Direct evidence for radical and triplet-state intermediates is provided. A correlation is found between the dynamics of reaction of the intermediate triplet states with the stabilities of the intermediate radicals.

AB - The mechanism of photodecomposition of aryl sulfones has been investigated by using both steady-state and time-resolved techniques. Direct evidence for radical and triplet-state intermediates is provided. A correlation is found between the dynamics of reaction of the intermediate triplet states with the stabilities of the intermediate radicals.

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Mechanistic Studies of the Photodecomposition of Arylmethyl Sulfones in Homogeneous and Micellar Solutions

Abstract

ASJC Scopus subject areas

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