Magnetic susceptibility of uniform microcrystals of platinum

R. F. Marzke; W. S. Glaunsinger; M. Bayard

doi:10.1016/0038-1098(76)91231-X

Magnetic susceptibility of uniform microcrystals of platinum

R. F. Marzke, W. S. Glaunsinger, M. Bayard

Physics

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37 Scopus citations

Abstract

The magnetic susceptibility of uniform platinum microcrystals having a mean diameter of 22.4 A has been measured by the Faraday technique from 1.5-200 K in fields of 2-13 kG. The susceptibility is independent of field, but becomes temperature dependent near 85 K and obeys the Curie law below about 20 K. The observed low-temperature behavior corresponds to about one unpaired electron per particle having spin-only paramagnetism. The results are compared to the theory of Denton et al., and it is concluded that the correct statistical distribution is the canonical, rather than the grand canonical, but that more extensive data are required to clearly differentiate among the various level-distribution ensembles.

Original language	English (US)
Pages (from-to)	1025-1030
Number of pages	6
Journal	Solid State Communications
Volume	18
Issue number	8
DOIs	https://doi.org/10.1016/0038-1098(76)91231-X
State	Published - 1976

ASJC Scopus subject areas

General Chemistry
Condensed Matter Physics
Materials Chemistry

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10.1016/0038-1098(76)91231-X

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title = "Magnetic susceptibility of uniform microcrystals of platinum",

abstract = "The magnetic susceptibility of uniform platinum microcrystals having a mean diameter of 22.4 A has been measured by the Faraday technique from 1.5-200 K in fields of 2-13 kG. The susceptibility is independent of field, but becomes temperature dependent near 85 K and obeys the Curie law below about 20 K. The observed low-temperature behavior corresponds to about one unpaired electron per particle having spin-only paramagnetism. The results are compared to the theory of Denton et al., and it is concluded that the correct statistical distribution is the canonical, rather than the grand canonical, but that more extensive data are required to clearly differentiate among the various level-distribution ensembles.",

author = "Marzke, {R. F.} and Glaunsinger, {W. S.} and M. Bayard",

year = "1976",

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T1 - Magnetic susceptibility of uniform microcrystals of platinum

AU - Marzke, R. F.

AU - Glaunsinger, W. S.

AU - Bayard, M.

PY - 1976

Y1 - 1976

N2 - The magnetic susceptibility of uniform platinum microcrystals having a mean diameter of 22.4 A has been measured by the Faraday technique from 1.5-200 K in fields of 2-13 kG. The susceptibility is independent of field, but becomes temperature dependent near 85 K and obeys the Curie law below about 20 K. The observed low-temperature behavior corresponds to about one unpaired electron per particle having spin-only paramagnetism. The results are compared to the theory of Denton et al., and it is concluded that the correct statistical distribution is the canonical, rather than the grand canonical, but that more extensive data are required to clearly differentiate among the various level-distribution ensembles.

AB - The magnetic susceptibility of uniform platinum microcrystals having a mean diameter of 22.4 A has been measured by the Faraday technique from 1.5-200 K in fields of 2-13 kG. The susceptibility is independent of field, but becomes temperature dependent near 85 K and obeys the Curie law below about 20 K. The observed low-temperature behavior corresponds to about one unpaired electron per particle having spin-only paramagnetism. The results are compared to the theory of Denton et al., and it is concluded that the correct statistical distribution is the canonical, rather than the grand canonical, but that more extensive data are required to clearly differentiate among the various level-distribution ensembles.

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JO - Solid State Communications

JF - Solid State Communications

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Magnetic susceptibility of uniform microcrystals of platinum

Abstract

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