Lotus effect amplifies light-induced contact angle switching

Rohit Rosario, Devens Gust, Antonio Garcia, Mark Hayes, J. L. Taraci, T. Clement, J. W. Dailey, S. T. Picraux

Research output: Contribution to journalArticle

211 Scopus citations

Abstract

A rough surface morphology is shown to significantly amplify the light-induced change in water contact angle of a photoresponsive surface. Smooth Si surfaces and fractally rough Si nanowire surfaces grown on a Si substrate were studied, both coated with a hydrophobic monolayer containing photochromic spiropyran molecules. Under visible irradiation the spiropyran is in a closed, hydrophobic form, whereas UV irradiation converts the spiropyran to a polar, hydrophilic form, reducing the contact angle. The superhydrophobic nanowire surface both amplifies the light-induced contact angle change by a factor of 2 relative to a smooth surface and reduces the contact angle hysteresis. As a result the UV-induced advancing contact angle is lower than the receding contact angle under visible irradiation, allowing water drops to be moved solely under the influence of a UV-visible light gradient. The amplification of the reversible light-induced wetting angle change was predicted using the Wenzel model for fractally rough surfaces. The model and amplification effects are expected to apply to other types of stimuli-induced contact angle changes such as that by heat or electrical potentials.

Original languageEnglish (US)
Pages (from-to)12640-12642
Number of pages3
JournalJournal of Physical Chemistry B
Volume108
Issue number34
DOIs
StatePublished - Aug 26 2004

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Surfaces, Coatings and Films
  • Materials Chemistry

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  • Cite this

    Rosario, R., Gust, D., Garcia, A., Hayes, M., Taraci, J. L., Clement, T., Dailey, J. W., & Picraux, S. T. (2004). Lotus effect amplifies light-induced contact angle switching. Journal of Physical Chemistry B, 108(34), 12640-12642. https://doi.org/10.1021/jp0473568