Lewis acid promoted Kharasch-type additions of 3-bromoacetyl-2- oxazolidinone to cycloalkenes

Ivanka K. Kavrakova, Jeremy Mills

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

Radical ytterbium trifluoromethanesulfonate promoted atom-transfer additions of 3-bromoacetyl-2-oxazolidinone to several cycloalkenes proceeded smoothly to give functionalised cycloalkane derivatives in good yields and stereoselectivities. All products were easily and cleanly debrominated with tri(trimethylsilyl)silane to the corresponding stable cycloalkylacetic acid derivatives.

Original languageEnglish (US)
Pages (from-to)59-61
Number of pages3
JournalJournal of Chemical Research
Issue number1
StatePublished - Jan 2005
Externally publishedYes

Fingerprint

Cycloparaffins
Oxazolidinones
Lewis Acids
Ytterbium
Derivatives
Silanes
Stereoselectivity
Atoms
Acids

Keywords

  • Cycloalkenes
  • Lewis acids
  • Oxazolidinones
  • Radical additions
  • Stereoselection

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Lewis acid promoted Kharasch-type additions of 3-bromoacetyl-2- oxazolidinone to cycloalkenes. / Kavrakova, Ivanka K.; Mills, Jeremy.

In: Journal of Chemical Research, No. 1, 01.2005, p. 59-61.

Research output: Contribution to journalArticle

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