Ledge-flow-controlled catalyst interface dynamics during Si nanowire growth

Stephan Hofmann, Renu Sharma, Christoph T. Wirth, Felipe Cervantes-Sodi, Caterina Ducati, Takeshi Kasama, Rafal E. Dunin-Borkowski, Jeffery Drucker, Peter Bennett, John Robertson

Research output: Contribution to journalArticle

210 Scopus citations

Abstract

Self-assembled nanowires offer the prospect of accurate and scalable device engineering at an atomistic scale for applications in electronics, photonics and biology. However, deterministic nanowire growth and the control of dopant profiles and heterostructures are limited by an incomplete understanding of the role of commonly used catalysts and specifically of their interface dynamics. Although catalytic chemical vapour deposition of nanowires below the eutectic temperature has been demonstrated in many semiconductor-catalyst systems, growth from solid catalysts is still disputed and the overall mechanism is largely unresolved. Here, we present a video-rate environmental transmission electron microscopy study of Si nanowire formation from Pd silicide crystals under disilane exposure. A Si crystal nucleus forms by phase separation, as observed for the liquid Au-Si system, which we use as a comparative benchmark. The dominant coherent Pd silicide/Si growth interface subsequently advances by lateral propagation of ledges, driven by catalytic dissociation of disilane and coupled Pd and Si diffusion. Our results establish an atomistic framework for nanowire assembly from solid catalysts, relevant also to their contact formation.

Original languageEnglish (US)
Pages (from-to)372-375
Number of pages4
JournalNature materials
Volume7
Issue number5
DOIs
StatePublished - May 2008

ASJC Scopus subject areas

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics
  • Mechanics of Materials
  • Mechanical Engineering

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    Hofmann, S., Sharma, R., Wirth, C. T., Cervantes-Sodi, F., Ducati, C., Kasama, T., Dunin-Borkowski, R. E., Drucker, J., Bennett, P., & Robertson, J. (2008). Ledge-flow-controlled catalyst interface dynamics during Si nanowire growth. Nature materials, 7(5), 372-375. https://doi.org/10.1038/nmat2140