Lattice measurement and alloy compositions in metal and bimetallic nanoparticles

S. C Y Tsen, P. A. Crozier, J. Liu

Research output: Contribution to journalArticle

40 Citations (Scopus)

Abstract

A new reliable method for determining the lattice spacings of metallic and bimetallic nanoparticles in phase contrast high resolution electron microscopy (HREM) images was developed. In this study, we discuss problems in applying HREM techniques to single metal (Pt and Au) and bimetallic (AuPd) nanoparticles of unknown shapes and random orientations. Errors arising from particle tilt and edge effects are discussed and analysis criteria are presented to reduce these errors in measuring the lattice parameters of nanoparticles. The accuracy of an individual particle lattice measurement is limited by an effective standard deviation which depends on the size of the individual nanoparticle. For example, the standard deviation for 20-30Å Pt or Au nanoparticles is about 1.5%. To increase the accuracy in determining the lattice spacings of nanoparticles, statistical methods have to be used to obtain the average lattice spacing of an ensemble of nanoparticles. We measured approximately 100 nanoparticles with sizes in the range of 20-30Å and found that the mean lattice spacing can be determined to within 0.2%. By applying Vegard's law to the AuPd bimetallic systems we successfully detected the presence of alloying. For 30Å nanoparticles, the estimated ultimate error in determining the composition of the AuPd alloy is about 3% provided that at least 100 particles are measured. Finally, the challenges in determining the presence of more than one alloy phases in bimetallic nanoparticle systems were also discussed.

Original languageEnglish (US)
Pages (from-to)63-72
Number of pages10
JournalUltramicroscopy
Volume98
Issue number1
DOIs
StatePublished - Dec 2003

Fingerprint

Metals
Nanoparticles
nanoparticles
Chemical analysis
metals
spacing
High resolution electron microscopy
standard deviation
electron microscopy
high resolution
phase contrast
Alloying
alloying
Lattice constants
lattice parameters
Statistical methods

Keywords

  • Bimetallic nanoparticles
  • Lattice

ASJC Scopus subject areas

  • Materials Science(all)
  • Instrumentation

Cite this

Lattice measurement and alloy compositions in metal and bimetallic nanoparticles. / Tsen, S. C Y; Crozier, P. A.; Liu, J.

In: Ultramicroscopy, Vol. 98, No. 1, 12.2003, p. 63-72.

Research output: Contribution to journalArticle

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