TY - JOUR
T1 - Lamellar reaction phenomena
T2 - from intercalation to nanomaterials formation
AU - McKelvy, Michael J.
AU - Sharma, Renu
AU - Chizmeshya, Andrew
N1 - Funding Information:
We thank the National Science Foundation for support through Grant DMR 91-06792, the National Energy Technology Laboratory for support through Grants DE-FG26-98FT40112 and DE-FG26-99FT40580 and Argonne National Laboratory Contract 1F-01262 and acknowledgement is made to the donors of the Petroleum Research Fund, administered by the American Chemical Society, for partial support of this research. We also thank the Center for Solid State Science for use of the Center for High Resolution Electron Microscopy and the Goldwater Materials Science Laboratories, including the Materials Facility, the Goldwater Materials Visualization Facility, and the Materials Science Electron Microscope Laboratory, and the Department of Chemistry and Biochemistry for use of the X-ray Diffraction Facility.
PY - 2006/5
Y1 - 2006/5
N2 - Lamellar reaction processes govern the formation and properties of a wide range of materials of fundamental and technological interest, offering the potential to control the structure, composition and dimension of materials down to the nanoscale. Environmental transmission electron microscopy, complementary investigations, and atomistic modeling have been combined to explore the mechanisms that control these processes. Model transition metal disulfide (e.g. TS2, T=Ti,Ta) intercalation/deintercalation and lamellar hydroxide (e.g. Mg(OH)2) dehydroxylation/rehydroxylation reaction processes are compared to probe the effect of relatively strong and weak/transitory intralayer bonding on lamellar reaction processes. Intriguing similarities are observed even though the hydroxide lamella are destroyed and reform during dehydroxylation and rehydroxylation processes, respectively. Deintercalation and dehydroxylation occur via analogous empty gallery and oxide layer formation. Both processes generally progress via lamellar nucleation and growth, with growth progressing away from the lamellar nucleation site. Similarities extend to stage formation, with random/'stage-2-like' oxide and hydroxide layer ordering occurring in the lamellar oxyhydroxide regions that form. In contrast to stable host layers associated with intercalation processes, relatively weak/transitory intralayer bonding associated with lamellar dehydroxylation/rehydroxylation processes facilitates layer delamination, shearing, cracking, and nanoreconstruction during dehydroxylation, and, nanocrystal formation, intergrowth and the rapid 'annealing out' of lamellar defects that form during rehydroxylation.
AB - Lamellar reaction processes govern the formation and properties of a wide range of materials of fundamental and technological interest, offering the potential to control the structure, composition and dimension of materials down to the nanoscale. Environmental transmission electron microscopy, complementary investigations, and atomistic modeling have been combined to explore the mechanisms that control these processes. Model transition metal disulfide (e.g. TS2, T=Ti,Ta) intercalation/deintercalation and lamellar hydroxide (e.g. Mg(OH)2) dehydroxylation/rehydroxylation reaction processes are compared to probe the effect of relatively strong and weak/transitory intralayer bonding on lamellar reaction processes. Intriguing similarities are observed even though the hydroxide lamella are destroyed and reform during dehydroxylation and rehydroxylation processes, respectively. Deintercalation and dehydroxylation occur via analogous empty gallery and oxide layer formation. Both processes generally progress via lamellar nucleation and growth, with growth progressing away from the lamellar nucleation site. Similarities extend to stage formation, with random/'stage-2-like' oxide and hydroxide layer ordering occurring in the lamellar oxyhydroxide regions that form. In contrast to stable host layers associated with intercalation processes, relatively weak/transitory intralayer bonding associated with lamellar dehydroxylation/rehydroxylation processes facilitates layer delamination, shearing, cracking, and nanoreconstruction during dehydroxylation, and, nanocrystal formation, intergrowth and the rapid 'annealing out' of lamellar defects that form during rehydroxylation.
KW - A. Inorganic compounds
KW - A. Multilayers
KW - C. Electron microscopy
KW - D. Lattice dynamics
KW - D. Microstructure
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U2 - 10.1016/j.jpcs.2006.01.079
DO - 10.1016/j.jpcs.2006.01.079
M3 - Article
AN - SCOPUS:33744907061
SN - 0022-3697
VL - 67
SP - 888
EP - 895
JO - Journal of Physics and Chemistry of Solids
JF - Journal of Physics and Chemistry of Solids
IS - 5-6
ER -