TY - JOUR
T1 - Lamellar Ceramic Semicrystalline-Polymer Composite Fabricated by Freeze Casting
AU - Huang, Jiacheng
AU - Xu, Zhe
AU - Moreno, Salvador
AU - Morsali, Seyedreza
AU - Zhou, Zhong
AU - Daryadel, Soheil
AU - Baniasadi, Mahmoud
AU - Qian, Dong
AU - Minary-Jolandan, Majid
N1 - Publisher Copyright:
© 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
PY - 2017/8
Y1 - 2017/8
N2 - Understanding the role of ductile polymer phase in mechanical behavior of bioinspired hybrid composites is an important step toward development of materials with damage tolerant properties. Herein, the authors report on fabrication and characterization of a bioinspired lamellar composite by incorporation of a semicrystalline polymer into a freeze casted scaffold. The elastic modulus and ductility of the polymer phase can be changed by more than three and 55 times, respectively, in addition to 42 folds decrease in modulus of toughness, by thermal annealing post-processing, after infiltration into the freeze casted ceramic scaffold. The results show that although polymer phase affects the fracture toughness and flexural behavior of the composite, the drastic changes in mechanical properties of the polymer phase has only marginal effect in the resulted properties of the composite. The authors use in situ SEM experiments and finite element simulation to investigate the deformation mechanism and the effect of the polymer phase on the distribution of stress in the fabricated composites.
AB - Understanding the role of ductile polymer phase in mechanical behavior of bioinspired hybrid composites is an important step toward development of materials with damage tolerant properties. Herein, the authors report on fabrication and characterization of a bioinspired lamellar composite by incorporation of a semicrystalline polymer into a freeze casted scaffold. The elastic modulus and ductility of the polymer phase can be changed by more than three and 55 times, respectively, in addition to 42 folds decrease in modulus of toughness, by thermal annealing post-processing, after infiltration into the freeze casted ceramic scaffold. The results show that although polymer phase affects the fracture toughness and flexural behavior of the composite, the drastic changes in mechanical properties of the polymer phase has only marginal effect in the resulted properties of the composite. The authors use in situ SEM experiments and finite element simulation to investigate the deformation mechanism and the effect of the polymer phase on the distribution of stress in the fabricated composites.
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U2 - 10.1002/adem.201700214
DO - 10.1002/adem.201700214
M3 - Article
AN - SCOPUS:85019565805
SN - 1438-1656
VL - 19
JO - Advanced Engineering Materials
JF - Advanced Engineering Materials
IS - 8
M1 - 1700214
ER -