Laboratory measurement of the permanent electric dipole moment of gas-phase CuO in its X 2Π state

Timothy Steimle; D. F. Nachman; D. A. Fletcher

doi:10.1063/1.453541

Laboratory measurement of the permanent electric dipole moment of gas-phase CuO in its X ²Π state

Timothy Steimle, D. F. Nachman, D. A. Fletcher

Molecular Sciences, School of (SMS)

Research output: Contribution to journal › Article › peer-review

3 Scopus citations

Abstract

A sub-Doppler optical Stark measurement of the P₁(1.5) branch feature of the A ²Σ^-(υ′ = 0)-X ²Π_3/2(υ = 0) subband system of gas phase copper monoxide, CuO, has been performed. The observed Stark shifts have been analyzed and a permanent electric dipole moment of 4.45 ± 0.30 D (1σ error estimate) for the X ²Π_3/2 state determined. The results are discussed in terms of the various bonding models proposed for CuO.

Original language	English (US)
Pages (from-to)	5670-5673
Number of pages	4
Journal	The Journal of chemical physics
Volume	87
Issue number	10
DOIs	https://doi.org/10.1063/1.453541
State	Published - Jan 1 1987

ASJC Scopus subject areas

Physics and Astronomy(all)
Physical and Theoretical Chemistry

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title = "Laboratory measurement of the permanent electric dipole moment of gas-phase CuO in its X 2Π state",

abstract = "A sub-Doppler optical Stark measurement of the P1(1.5) branch feature of the A 2Σ-(υ′ = 0)-X 2Π3/2(υ = 0) subband system of gas phase copper monoxide, CuO, has been performed. The observed Stark shifts have been analyzed and a permanent electric dipole moment of 4.45 ± 0.30 D (1σ error estimate) for the X 2Π3/2 state determined. The results are discussed in terms of the various bonding models proposed for CuO.",

author = "Timothy Steimle and Nachman, {D. F.} and Fletcher, {D. A.}",

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T1 - Laboratory measurement of the permanent electric dipole moment of gas-phase CuO in its X 2Π state

AU - Steimle, Timothy

AU - Nachman, D. F.

AU - Fletcher, D. A.

PY - 1987/1/1

Y1 - 1987/1/1

N2 - A sub-Doppler optical Stark measurement of the P1(1.5) branch feature of the A 2Σ-(υ′ = 0)-X 2Π3/2(υ = 0) subband system of gas phase copper monoxide, CuO, has been performed. The observed Stark shifts have been analyzed and a permanent electric dipole moment of 4.45 ± 0.30 D (1σ error estimate) for the X 2Π3/2 state determined. The results are discussed in terms of the various bonding models proposed for CuO.

AB - A sub-Doppler optical Stark measurement of the P1(1.5) branch feature of the A 2Σ-(υ′ = 0)-X 2Π3/2(υ = 0) subband system of gas phase copper monoxide, CuO, has been performed. The observed Stark shifts have been analyzed and a permanent electric dipole moment of 4.45 ± 0.30 D (1σ error estimate) for the X 2Π3/2 state determined. The results are discussed in terms of the various bonding models proposed for CuO.

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JO - Journal of Chemical Physics

JF - Journal of Chemical Physics

IS - 10

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Laboratory measurement of the permanent electric dipole moment of gas-phase CuO in its X ²Π state

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