Kinetic parameter estimation and fluctuation analysis of CO at SnO 2 single nanowires

Gerhard Tulzer, Stefan Baumgartner, Elise Brunet, Giorgio C. Mutinati, Stephan Steinhauer, Anton Köck, Paolo E. Barbano, Clemens Heitzinger

Research output: Contribution to journalArticle

25 Scopus citations

Abstract

In this work, we present calculated numerical values for the kinetic parameters governing adsorption/desorption processes of carbon monoxide at tin dioxide single-nanowire gas sensors. The response of such sensors to pulses of 50 ppm carbon monoxide in nitrogen is investigated at different temperatures to extract the desired information. A rate-equation approach is used to model the reaction kinetics, which results in the problem of determining coefficients in a coupled system of nonlinear ordinary differential equations. The numerical values are computed by inverse-modeling techniques and are then used to simulate the sensor response. With our model, the dynamic response of the sensor due to the gas-surface interaction can be studied in order to find the optimal setup for detection, which is an important step towards selectivity of these devices. We additionally investigate the noise in the current through the nanowire and its changes due to the presence of carbon monoxide in the sensor environment. Here, we propose the use of a wavelet transform to decompose the signal and analyze the noise in the experimental data. This method indicates that some fluctuations are specific for the gas species investigated here.

Original languageEnglish (US)
Article number315501
JournalNanotechnology
Volume24
Issue number31
DOIs
StatePublished - Aug 9 2013

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ASJC Scopus subject areas

  • Bioengineering
  • Chemistry(all)
  • Materials Science(all)
  • Mechanics of Materials
  • Mechanical Engineering
  • Electrical and Electronic Engineering

Cite this

Tulzer, G., Baumgartner, S., Brunet, E., Mutinati, G. C., Steinhauer, S., Köck, A., Barbano, P. E., & Heitzinger, C. (2013). Kinetic parameter estimation and fluctuation analysis of CO at SnO 2 single nanowires. Nanotechnology, 24(31), [315501]. https://doi.org/10.1088/0957-4484/24/31/315501