Abstract

The intermediate band (IB) solar cell offers a route to higher efficiency solar cells by inserting a band into the band gap of large band gap material. Theoretically, the open circuit voltage of the IB solar cell is close to that of the high band gap regions, and the current is increased through the addition of the intermediate band. However, experimental results have shown a decrease in the open circuit voltage, and a small increase in the short circuit current. We explain the decrease in Voc, as well as the small increase in Jsc though a thermodynamic and physical model. These models show that both these results are consistent with the absence of multiple quasi-Fermi levels. Because of the importance of realizing multiple quasi-Fermi levels, the definitive proof of this effect is critical in demonstrating the viability of the intermediate band, but show that demonstrated indicators of an intermediate band may be caused by other physical mechanisms. Instead, a key indicator of a quasi-Fermi level separation not explained by non-idealities are the features associated with the intermediate band quasi-Fermi level crossing the intermediate band energy level, demonstrated by shifting peak energies.

Original languageEnglish (US)
Title of host publicationProgram - 38th IEEE Photovoltaic Specialists Conference, PVSC 2012
Pages641-646
Number of pages6
DOIs
StatePublished - Nov 26 2012
Event38th IEEE Photovoltaic Specialists Conference, PVSC 2012 - Austin, TX, United States
Duration: Jun 3 2012Jun 8 2012

Publication series

NameConference Record of the IEEE Photovoltaic Specialists Conference
ISSN (Print)0160-8371

Other

Other38th IEEE Photovoltaic Specialists Conference, PVSC 2012
CountryUnited States
CityAustin, TX
Period6/3/126/8/12

ASJC Scopus subject areas

  • Control and Systems Engineering
  • Industrial and Manufacturing Engineering
  • Electrical and Electronic Engineering

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  • Cite this

    Bremner, S., Ghosh, K., Ekins-Daukes, N., Honsberg, C., & Goodnick, S. (2012). Issues in the physical measurement of the intermediate band effect. In Program - 38th IEEE Photovoltaic Specialists Conference, PVSC 2012 (pp. 641-646). [6317692] (Conference Record of the IEEE Photovoltaic Specialists Conference). https://doi.org/10.1109/PVSC.2012.6317692