Ionic conductivities of hybrid inorganic sulfide-polyether electrolytes

Akitoshi Hayashi, Limin Wang, Charles Angell

Research output: Contribution to journalArticle

9 Citations (Scopus)

Abstract

Hybrid polymers combining P2S5 moieties with oligoether spacers have been prepared, and the conductivities and glass transition temperatures of their solutions of lithium salts have been examined. The materials are highly viscous but mostly not rubbery. A high ambient temperature conductivity of 10-3.9 S cm-1 was obtained with LiTFSI dissolved in the sulfide-PEO matrix. The decoupling of Li+ motion from the polymer segmental motion is demonstrated, suggesting that, in certain cases, the transport number for Li+ ion in the sulfide-PEO matrix will be much higher than in a typical PEO-based salt-in-polymer system.

Original languageEnglish (US)
Pages (from-to)2003-2008
Number of pages6
JournalElectrochimica Acta
Volume48
Issue number14-16 SPEC.
DOIs
StatePublished - Jun 30 2003

Fingerprint

Polyethers
Sulfides
Ionic conductivity
Polyethylene oxides
Electrolytes
Polymers
Salts
Lithium
Ions
Temperature

Keywords

  • Hybrid polymers
  • Ionic conductivities
  • Sulfide-polyether electrolytes

ASJC Scopus subject areas

  • Chemical Engineering(all)
  • Analytical Chemistry
  • Electrochemistry

Cite this

Ionic conductivities of hybrid inorganic sulfide-polyether electrolytes. / Hayashi, Akitoshi; Wang, Limin; Angell, Charles.

In: Electrochimica Acta, Vol. 48, No. 14-16 SPEC., 30.06.2003, p. 2003-2008.

Research output: Contribution to journalArticle

Hayashi, Akitoshi ; Wang, Limin ; Angell, Charles. / Ionic conductivities of hybrid inorganic sulfide-polyether electrolytes. In: Electrochimica Acta. 2003 ; Vol. 48, No. 14-16 SPEC. pp. 2003-2008.
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