Investigation of formally zerovalent Triphos iron complexes

Tufan K. Mukhopadhyay, Russell K. Feller, Francisca N. Rein, Neil J. Henson, Nathan C. Smythe, Ryan Trovitch, John C. Gordon

Research output: Contribution to journalArticlepeer-review

8 Scopus citations

Abstract

The reduction of Triphos [PhP(CH2CH2PPh2)2] iron halide complexes has been explored, yielding formally zerovalent (κ3-Triphos)Fe(κ2-Triphos) and (κ3-Triphos)Fe(κ2-Bpy). Electrochemical analysis, coupled with the metrical parameters of (κ3-Triphos)Fe(κ2-Bpy), reveal an electronic structure consistent with a π-radical monoanion bipyridine chelate that is antiferromagnetically coupled to a low spin, Fe(i) metal center.

Original languageEnglish (US)
Pages (from-to)8670-8672
Number of pages3
JournalChemical Communications
Volume48
Issue number69
DOIs
StatePublished - Aug 1 2012

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

Fingerprint Dive into the research topics of 'Investigation of formally zerovalent Triphos iron complexes'. Together they form a unique fingerprint.

Cite this