Investigation of dilute-nitride alloys of GaAsNx (0.01 <x <0.04) grown by MBE on GaAs (001) substrates for photovoltaic solar cell devices

Dinghao Tang, Gopi Krishna Vijaya, Akhil Mehrotra, Alex Freundlich, David Smith

Research output: Contribution to journalArticle

6 Scopus citations

Abstract

Dilute-nitride GaAsNx epilayers were grown on GaAs (001) substrates at temperatures of ∼450 °C using a radio-frequency plasma-assisted molecular/chemical beam exitaxy system. The concentration of nitrogen incorporated into the films was varied in the range between 0.01 and 0.04. High-resolution electron microscopy was used to determine the cross-sectional morphology of the epilayers, and Z-contrast imaging showed that the incorporated nitrogen was primarily interstitial. {110}-oriented microcracks, which resulted in strain relaxation, were observed in the sample with the highest N concentration ([N] ∼ 3.7%). Additionally, Z-contrast imaging indicated the formation of a thin, high-N quantum-well-like layer associated with initial ignition of the N-plasma. Significant N contamination of the GaAs barrier layers was observed in all samples, and could severely affect the carrier extraction and transport properties in future targeted devices. Dilute-nitride quantum-well-based photovoltaic solar cells were fabricated having a band-gap energy of 1.19 eV, which was attributed to the dilute-nitride layer.

Original languageEnglish (US)
Article number011210
JournalJournal of Vacuum Science and Technology B:Nanotechnology and Microelectronics
Volume34
Issue number1
DOIs
StatePublished - Jan 1 2016

ASJC Scopus subject areas

  • Electrical and Electronic Engineering
  • Process Chemistry and Technology
  • Electronic, Optical and Magnetic Materials
  • Surfaces, Coatings and Films
  • Materials Chemistry
  • Instrumentation

Fingerprint Dive into the research topics of 'Investigation of dilute-nitride alloys of GaAsN<sub>x</sub> (0.01 <x <0.04) grown by MBE on GaAs (001) substrates for photovoltaic solar cell devices'. Together they form a unique fingerprint.

  • Cite this