Intramolecular hydrogen bonding as a synthetic tool to induce chemical selectivity in acid catalyzed porphyrin synthesis

Jackson D. Megiatto; Dustin Patterson; Benjamin D. Sherman; Thomas Moore; Devens Gust; Ana Moore

doi:10.1039/c2cc31228j

Intramolecular hydrogen bonding as a synthetic tool to induce chemical selectivity in acid catalyzed porphyrin synthesis

Jackson D. Megiatto, Dustin Patterson, Benjamin D. Sherman, Thomas Moore, Devens Gust, Ana Moore

Research output: Contribution to journal › Article › peer-review

11 Scopus citations

Abstract

A straightforward procedure based on the formation of intramolecular hydrogen bonds to impart selectivity in the preparation of multi-functionalized porphyrins has been developed. To illustrate the concept, the synthesis of a biomimetic artificial photosynthetic model able to undergo electron and proton transfer reactions upon irradiation is reported.

Original language	English (US)
Pages (from-to)	4558-4560
Number of pages	3
Journal	Chemical Communications
Volume	48
Issue number	38
DOIs	https://doi.org/10.1039/c2cc31228j
State	Published - Apr 11 2012

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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title = "Intramolecular hydrogen bonding as a synthetic tool to induce chemical selectivity in acid catalyzed porphyrin synthesis",

abstract = "A straightforward procedure based on the formation of intramolecular hydrogen bonds to impart selectivity in the preparation of multi-functionalized porphyrins has been developed. To illustrate the concept, the synthesis of a biomimetic artificial photosynthetic model able to undergo electron and proton transfer reactions upon irradiation is reported.",

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AU - Megiatto, Jackson D.

AU - Patterson, Dustin

AU - Sherman, Benjamin D.

AU - Moore, Thomas

AU - Gust, Devens

AU - Moore, Ana

PY - 2012/4/11

Y1 - 2012/4/11

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AB - A straightforward procedure based on the formation of intramolecular hydrogen bonds to impart selectivity in the preparation of multi-functionalized porphyrins has been developed. To illustrate the concept, the synthesis of a biomimetic artificial photosynthetic model able to undergo electron and proton transfer reactions upon irradiation is reported.

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JO - Chemical Communications

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Intramolecular hydrogen bonding as a synthetic tool to induce chemical selectivity in acid catalyzed porphyrin synthesis

Abstract

ASJC Scopus subject areas

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