Interplay of metal-allyl and metal-metal bonding in dimolybdenum allyl complexes

Ryan J. Trovitch; Kevin D. John; Richard L. Martin; Stephen J. Obrey; Brian L. Scott; Alfred P. Sattelberger; R. Thomas Baker

doi:10.1039/b908032e

Interplay of metal-allyl and metal-metal bonding in dimolybdenum allyl complexes

Ryan J. Trovitch, Kevin D. John, Richard L. Martin, Stephen J. Obrey, Brian L. Scott, Alfred P. Sattelberger, R. Thomas Baker

Research output: Contribution to journal › Article › peer-review

4 Scopus citations

Abstract

Addition of PMe₃ to Mo₂(allyl)₄ afforded Mo₂(allyl)₄(PMe₃)₂, in which two of the allyl groups adopt an unprecedented μ₂-η¹, η³ bonding mode; theoretical studies elucidate the roles of the σ- and π-donor ligands in the interplay of metal-allyl and metal-metal bonding.

Original language	English (US)
Pages (from-to)	4206-4208
Number of pages	3
Journal	Chemical Communications
Issue number	28
DOIs	https://doi.org/10.1039/b908032e
State	Published - 2009
Externally published	Yes

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/b908032e

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title = "Interplay of metal-allyl and metal-metal bonding in dimolybdenum allyl complexes",

abstract = "Addition of PMe3 to Mo2(allyl)4 afforded Mo2(allyl)4(PMe3)2, in which two of the allyl groups adopt an unprecedented μ2-η1, η3 bonding mode; theoretical studies elucidate the roles of the σ- and π-donor ligands in the interplay of metal-allyl and metal-metal bonding.",

author = "Trovitch, {Ryan J.} and John, {Kevin D.} and Martin, {Richard L.} and Obrey, {Stephen J.} and Scott, {Brian L.} and Sattelberger, {Alfred P.} and Baker, {R. Thomas}",

year = "2009",

doi = "10.1039/b908032e",

language = "English (US)",

pages = "4206--4208",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "28",

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TY - JOUR

T1 - Interplay of metal-allyl and metal-metal bonding in dimolybdenum allyl complexes

AU - Trovitch, Ryan J.

AU - John, Kevin D.

AU - Martin, Richard L.

AU - Obrey, Stephen J.

AU - Scott, Brian L.

AU - Sattelberger, Alfred P.

AU - Baker, R. Thomas

PY - 2009

Y1 - 2009

N2 - Addition of PMe3 to Mo2(allyl)4 afforded Mo2(allyl)4(PMe3)2, in which two of the allyl groups adopt an unprecedented μ2-η1, η3 bonding mode; theoretical studies elucidate the roles of the σ- and π-donor ligands in the interplay of metal-allyl and metal-metal bonding.

AB - Addition of PMe3 to Mo2(allyl)4 afforded Mo2(allyl)4(PMe3)2, in which two of the allyl groups adopt an unprecedented μ2-η1, η3 bonding mode; theoretical studies elucidate the roles of the σ- and π-donor ligands in the interplay of metal-allyl and metal-metal bonding.

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U2 - 10.1039/b908032e

DO - 10.1039/b908032e

M3 - Article

C2 - 19585022

AN - SCOPUS:67650465843

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EP - 4208

JO - Chemical Communications

JF - Chemical Communications

IS - 28

ER -

Interplay of metal-allyl and metal-metal bonding in dimolybdenum allyl complexes

Abstract

ASJC Scopus subject areas

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